Literature DB >> 25873268

Chemically and electrochemically induced expansion and contraction of a ferrocene rotor.

Synøve Ø Scottwell1, Anastasia B S Elliott, Karl J Shaffer, Ayman Nafady, C John McAdam, Keith C Gordon, James D Crowley.   

Abstract

A 2,2'-bipyridine-appended ferrocene rotor, 1,1'-di(5-yl-ethynyl-2,2'-bipyridine)ferrocene, can be switched from a folded/stacked (syn) conformation to an extended/unstacked (anti) conformation by the addition of [Cu(CH3CN)4](PF6) and 6,6'-dimesityl-2,2'-bipyridine. This extension and contraction process was completely reversible and could be triggered either chemically or electrochemically.

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Year:  2015        PMID: 25873268     DOI: 10.1039/c5cc01973g

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  4 in total

1.  Synthesis and Light-Induced Actuation of Photo-Labile 2-Pyridyl-1,2,3-Triazole Ru(bis-bipyridyl) Appended Ferrocene Rotors.

Authors:  James A Findlay; Jonathan E Barnsley; Keith C Gordon; James D Crowley
Journal:  Molecules       Date:  2018-08-14       Impact factor: 4.411

Review 2.  Ferrocene and Transition Metal Bis(Dicarbollides) as Platform for Design of Rotatory Molecular Switches.

Authors:  Igor B Sivaev
Journal:  Molecules       Date:  2017-12-11       Impact factor: 4.411

3.  Fast, solvent-free synthesis of ferrocene-containing organic cages via dynamic covalent chemistry in the solid state.

Authors:  Tom Kunde; Tobias Pausch; Piotr A Guńka; Maurycy Krzyżanowski; Artur Kasprzak; Bernd M Schmidt
Journal:  Chem Sci       Date:  2022-02-03       Impact factor: 9.825

4.  Ionization of Decamethylmanganocene: Insights from the DFT-Assisted Laser Spectroscopy.

Authors:  Sergey Ketkov; Sheng-Yuan Tzeng; Elena Rychagova; Wen-Bih Tzeng
Journal:  Molecules       Date:  2022-09-22       Impact factor: 4.927

  4 in total

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