Literature DB >> 25867113

Palladium-catalyzed asymmetric reductive heck reaction of aryl halides.

Guizhou Yue1,2, Kaining Lei1, Hajime Hirao1, Jianrong Steve Zhou3.   

Abstract

Asymmetric reductive Heck reaction of aryl halides is realized in high stereoselectivity. Hydrogen-bond donors, trialkylammonium salts in a glycol solvent, were used to promote halide dissociation from neutral arylpalladium complexes to access cationic, stereoselective pathways.
© 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  asymmetric catalysis; hydrogen bonding; olefins; palladium; synthetic methods

Year:  2015        PMID： 25867113     DOI： 10.1002/anie.201501712

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  7 in total

1.  Practical Intermolecular Hydroarylation of Terminal Alkenes via Reductive Heck Coupling.

Authors:  John A Gurak; Keary M Engle
Journal:  ACS Catal       Date:  2018-08-24       Impact factor: 13.084

2.  Palladium-Catalyzed Reductive Heck Coupling of Alkenes.

Authors:  Lucas J Oxtoby; John A Gurak; Steven R Wisniewski; Martin D Eastgate; Keary M Engle
Journal:  Trends Chem       Date:  2019-06-20

3.  Rh-catalyzed Reagent-Free Ring Expansion of Cyclobutenones and Benzocyclobutenones.

Authors:  Peng-Hao Chen; Joshua Sieber; Chris H Senanayake; Guangbin Dong
Journal:  Chem Sci       Date:  2015-07-10       Impact factor: 9.825

4.  Efficient kinetic resolution in the asymmetric transfer hydrogenation of 3-aryl-indanones: applications to a short synthesis of (+)-indatraline and a formal synthesis of (R)-tolterodine.

Authors:  Songsoon Park; Hyeon-Kyu Lee
Journal:  RSC Adv       Date:  2021-06-30       Impact factor: 3.361

5.  Introducing unactivated acyclic internal aliphatic olefins into a cobalt catalyzed allylic selective dehydrogenative Heck reaction.

Authors:  Soham Maity; Pravas Dolui; Rajesh Kancherla; Debabrata Maiti
Journal:  Chem Sci       Date:  2017-05-16       Impact factor: 9.825

6.  Enantioselective synthesis of quaternary 3,4-dihydroisoquinolinones via Heck carbonylation reactions: development and application to the synthesis of Minalrestat analogues.

Authors:  Cang Cheng; Bin Wan; Bo Zhou; Yichao Gu; Yanghui Zhang
Journal:  Chem Sci       Date:  2019-09-03       Impact factor: 9.825

7.  Bifunctional thiourea-catalyzed asymmetric [3 + 2] annulation reactions of 2-isothiocyanato-1-indanones with barbiturate-based olefins.

Authors:  Jiang-Song Zhai; Da-Ming Du
Journal:  Beilstein J Org Chem       Date:  2022-01-04       Impact factor: 2.883
  7 in total

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