| Literature DB >> 25865826 |
Eric G Moschetta1, Solymar Negretti2, Kathryn M Chepiga2, Nicholas A Brunelli1,2, Ying Labreche1, Yan Feng1, Fateme Rezaei1, Ryan P Lively1, William J Koros1, Huw M L Davies3, Christopher W Jones4.
Abstract
Flexible composite polymer/oxide hollow fibers are used as flow reactors for heterogeneously catalyzed reactions in organic synthesis. The fiber synthesis allows for a variety of supported catalysts to be embedded in the walls of the fibers, thus leading to a diverse set of reactions that can be catalyzed in flow. Additionally, the fiber synthesis is scalable (e.g. several reactor beds containing many fibers in a module may be used) and thus they could potentially be used for the large-scale production of organic compounds. Incorporating heterogeneous catalysts in the walls of the fibers presents an alternative to a traditional packed-bed reactor and avoids large pressure drops, which is a crucial challenge when employing microreactors.Entities:
Keywords: flow chemistry; heterogeneous catalysis; hollow fibers; organic synthesis; rhodium
Year: 2015 PMID: 25865826 DOI: 10.1002/anie.201500841
Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN: 1433-7851 Impact factor: 15.336