Literature DB >> 25865826

Composite polymer/oxide hollow fiber contactors: versatile and scalable flow reactors for heterogeneous catalytic reactions in organic synthesis.

Eric G Moschetta1, Solymar Negretti2, Kathryn M Chepiga2, Nicholas A Brunelli1,2, Ying Labreche1, Yan Feng1, Fateme Rezaei1, Ryan P Lively1, William J Koros1, Huw M L Davies3, Christopher W Jones4.   

Abstract

Flexible composite polymer/oxide hollow fibers are used as flow reactors for heterogeneously catalyzed reactions in organic synthesis. The fiber synthesis allows for a variety of supported catalysts to be embedded in the walls of the fibers, thus leading to a diverse set of reactions that can be catalyzed in flow. Additionally, the fiber synthesis is scalable (e.g. several reactor beds containing many fibers in a module may be used) and thus they could potentially be used for the large-scale production of organic compounds. Incorporating heterogeneous catalysts in the walls of the fibers presents an alternative to a traditional packed-bed reactor and avoids large pressure drops, which is a crucial challenge when employing microreactors.
© 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  flow chemistry; heterogeneous catalysis; hollow fibers; organic synthesis; rhodium

Year:  2015        PMID: 25865826     DOI: 10.1002/anie.201500841

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN: 1433-7851            Impact factor:   15.336


  6 in total

1.  Finding Opportunities from Surprises and Failures. Development of Rhodium-Stabilized Donor/Acceptor Carbenes and Their Application to Catalyst-Controlled C-H Functionalization.

Authors:  Huw M L Davies
Journal:  J Org Chem       Date:  2019-10-10       Impact factor: 4.354

2.  Continuous-Flow Synthesis and Derivatization of Aziridines through Palladium-Catalyzed C(sp(3) )-H Activation.

Authors:  Jacek Zakrzewski; Adam P Smalley; Mikhail A Kabeshov; Matthew J Gaunt; Alexei A Lapkin
Journal:  Angew Chem Int Ed Engl       Date:  2016-06-15       Impact factor: 15.336

3.  A Modular Flow Design for the meta-Selective C-H Arylation of Anilines.

Authors:  Hannes P L Gemoets; Gabriele Laudadio; Kirsten Verstraete; Volker Hessel; Timothy Noël
Journal:  Angew Chem Int Ed Engl       Date:  2017-05-22       Impact factor: 15.336

4.  Rapid Asymmetric Synthesis of Disubstituted Allenes by Coupling of Flow-Generated Diazo Compounds and Propargylated Amines.

Authors:  Jian-Siang Poh; Szabolcs Makai; Timo von Keutz; Duc N Tran; Claudio Battilocchio; Patrick Pasau; Steven V Ley
Journal:  Angew Chem Int Ed Engl       Date:  2017-01-11       Impact factor: 15.336

5.  Enzymatic synthesis of nucleoside analogues from uridines and vinyl esters in a continuous-flow microreactor.

Authors:  Li-Hua Du; Jia-Hong Shen; Zhen Dong; Na-Ni Zhou; Bing-Zhuo Cheng; Zhi-Min Ou; Xi-Ping Luo
Journal:  RSC Adv       Date:  2018-04-03       Impact factor: 4.036

6.  Recyclable heterogeneous metal foil-catalyzed cyclopropenation of alkynes and diazoacetates under solvent-free mechanochemical reaction conditions.

Authors:  Longrui Chen; Devonna Leslie; Michael G Coleman; James Mack
Journal:  Chem Sci       Date:  2018-04-24       Impact factor: 9.825

  6 in total

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