Literature DB >> 25854194

Preparation, structure, and versatile reactivity of pseudocyclic benziodoxole triflate, new hypervalent iodine reagent.

Akira Yoshimura1, Khiem C Nguyen, Scott C Klasen, Akio Saito, Victor N Nemykin, Viktor V Zhdankin.   

Abstract

A new pseudocyclic triflate derivative of benziodoxole (IBA-OTf) was prepared and characterized by X-ray analysis. This highly electrophilic reagent readily reacts with various organic substrates to give the corresponding products in good yields. Furthermore, IBA-OTf can be used as a catalyst with m-chloroperoxybenzoic acid as the terminal oxidant.

Entities:  

Year:  2015        PMID： 25854194     DOI： 10.1039/c5cc02009c

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  3 in total

1.  Borylated oximes: versatile building blocks for organic synthesis.

Authors:  Sean K Liew; Aleksandra Holownia; Diego B Diaz; Philip A Cistrone; Philip E Dawson; Andrei K Yudin
Journal:  Chem Commun (Camb)       Date:  2017-09-29       Impact factor: 6.222

2.  Oxidative cycloaddition of hydroxamic acids with dienes or guaiacols mediated by iodine(III) reagents.

Authors:  Hisato Shimizu; Akira Yoshimura; Keiichi Noguchi; Victor N Nemykin; Viktor V Zhdankin; Akio Saito
Journal:  Beilstein J Org Chem       Date:  2018-02-28       Impact factor: 2.883

3.  Efficient Catalytic Synthesis of Condensed Isoxazole Derivatives via Intramolecular Oxidative Cycloaddition of Aldoximes.

Authors:  Irina A Mironova; Valentine G Nenajdenko; Pavel S Postnikov; Akio Saito; Mekhman S Yusubov; Akira Yoshimura
Journal:  Molecules       Date:  2022-06-16       Impact factor: 4.927
  3 in total

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