Literature DB >> 25853234

Remarkably stable chelating bis-N-heterocyclic carbene adducts of phosphorus(i) cations.

Justin F Binder1, Ala'aeddeen Swidan, Martin Tang, Jennifer H Nguyen, Charles L B Macdonald.   

Abstract

A convenient one-pot synthesis of chelating bis-N-heterocyclic carbene-ligated P(I) salts is described. The solid state structures of these remarkably stable phosphamethine cyanine dyes with various N-alkyl groups and counter-anions are reported, and initial reactivity results are discussed.

Entities:  

Year:  2015        PMID： 25853234     DOI： 10.1039/c5cc00331h

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  3 in total

1.  Preparation and Reactivity of a Triphosphenium Bromide Salt: A Convenient and Stable Source of Phosphorus(I).

Authors:  Stephanie C Kosnik; Justin F Binder; Maxemilian C Nascimento; Charles L B Macdonald
Journal:  J Vis Exp       Date:  2016-11-22       Impact factor: 1.355

2.  Iron- and Cobalt-Catalyzed Synthesis of Carbene Phosphinidenes.

Authors:  Kuntal Pal; Oliver B Hemming; Benjamin M Day; Thomas Pugh; David J Evans; Richard A Layfield
Journal:  Angew Chem Int Ed Engl       Date:  2015-12-08       Impact factor: 15.336

3.  Reappraising Schmidpeter's bis(iminophosphoranyl)phosphides: coordination to transition metals and bonding analysis.

Authors:  Adrien T Normand; E Daiann Sosa Carrizo; Corentin Magnoux; Esteban Lobato; Hélène Cattey; Philippe Richard; Stéphane Brandès; Charles H Devillers; Anthony Romieu; Pierre Le Gendre; Paul Fleurat-Lessard
Journal:  Chem Sci       Date:  2020-10-26       Impact factor: 9.825
  3 in total

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