| Literature DB >> 25851041 |
Micke Lisbjerg1,2, Hennie Valkenier2, Bo M Jessen1, Hana Al-Kerdi1, Anthony P Davis2, Michael Pittelkow1.
Abstract
Biotin[6]uril hexaesters represent a new class of anionophores which operate solely through C-H···anion interactions. The use of soft H-bond donors favors the transport of less hydrophilic anions (e.g., Cl(-), NO3(-)) over hard, stongly hydrated anions (e.g., HCO3(-) and SO4(2-)). Especially relevant is the selectivity between chloride and bicarbonate, the major inorganic anions in biological systems.Entities:
Mesh:
Substances:
Year: 2015 PMID: 25851041 DOI: 10.1021/jacs.5b02306
Source DB: PubMed Journal: J Am Chem Soc ISSN: 0002-7863 Impact factor: 15.419