| Literature DB >> 25831154 |
Mayaka Maeno1,2, Norio Shibata2, Dominique Cahard1.
Abstract
An electrophilic trifluoromethylthiolation of allylic alcohols produces the corresponding allylic trifluoromethanesulfenates, which spontaneously rearrange into trifluoromethyl sulfoxides via a [2,3]-sigmatropic rearrangement. The reaction is straightforward and proceeds in good to high yields for the preparation of various allylic trifluoromethyl sulfoxides.Entities:
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Year: 2015 PMID： 25831154 DOI： 10.1021/acs.orglett.5b00750
Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005