Literature DB >> 25824578

C-H bonds phosphorylation of ketene dithioacetals.

Liping Zhu1, Hongmei Yu1, Quanping Guo1, Qiao Chen1, Zhaoqing Xu1, Rui Wang1,2.   

Abstract

C-H bond phosphorylation of ketene dithioacetals was achieved under transition-metal-free or AgNO3 mediated conditions. Synthetic transformations of the coupling product provided promising methods for the construction of highly functionalized phosphorylated N-heterocycles and tetrasubstituted alkenes.

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Year:  2015        PMID： 25824578     DOI： 10.1021/acs.orglett.5b00728

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  5 in total

1.  Direct phosphorylation of benzylic C-H bonds under transition metal-free conditions forming sp3C-P bonds.

Authors:  Qiang Li; Chang-Qiu Zhao; Tieqiao Chen; Li-Biao Han
Journal:  RSC Adv       Date:  2022-06-24       Impact factor: 4.036

2.  Metal-Free Vinyl C-H Sulfenylation/Alkyl Thiolation of Ketene Dithioacetals for the Synthesis of Polythiolated Alkenes.

Authors:  Leiling Deng; Yunyun Liu
Journal:  ACS Omega       Date:  2018-09-25

3.  Silver-catalyzed synthesis of β-fluorovinylphosphonates by phosphonofluorination of aromatic alkynes.

Authors:  Yajing Zhang; Qingshan Tian; Guozhu Zhang; Dayong Zhang
Journal:  Beilstein J Org Chem       Date:  2020-12-18       Impact factor: 2.883

4.  Cs2CO3-promoted defluorination and functionalization of α-CF3 carbonyl compounds in the presence of N-, O-, and/or S-nucleophiles.

Authors:  Yue Wu; Bingbing Zhang; Yinying Zheng; Yuheng Wang; Xinsheng Lei
Journal:  RSC Adv       Date:  2018-04-30       Impact factor: 3.361

5.  Metal-free synthesis of phosphinoylchroman-4-ones via a radical phosphinoylation-cyclization cascade mediated by K2S2O8.

Authors:  Qiang Liu; Weibang Lu; Guanqun Xie; Xiaoxia Wang
Journal:  Beilstein J Org Chem       Date:  2020-08-12       Impact factor: 2.883
  5 in total

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