| Literature DB >> 25813555 |
Christina Eller1, Gerald Kehr, Constantin G Daniliuc, Douglas W Stephan, Gerhard Erker.
Abstract
Reaction of bis(tert-butylethynyl)sulfide with the boron Lewis acid reagents X-B(C6F5)2 (X = CH3, Cl, C6F5) in pentane at r.t. gave the respective borylated thiophenes in a sequence of 1,1-carboboration reactions. In contrast, bis(phenylethynyl)sulfide reacted with B(C6F5)3 only in a 2 : 1 molar ratio to give a benzothiophene derivative.Entities:
Year: 2015 PMID： 25813555 DOI： 10.1039/c5cc01806d
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222