Literature DB >> 25812679

Visible light promoted carbodifluoroalkylation of allylic alcohols via concomitant 1,2-aryl migration.

Pan Xu1, Kaidong Hu, Zhangxi Gu, Yixiang Cheng, Chengjian Zhu.   

Abstract

A novel visible light promoted carbodifluoroalkylation of allylic alcohols is disclosed. A series of difluoro 1,5-dicarbonyl compounds were obtained through a tandem radical addition and 1,2-aryl migration process. Mechanistic analysis indicated that the 1,2-aryl rearrangement proceeded via a radical intermediate.

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Year:  2015        PMID： 25812679     DOI： 10.1039/c5cc01189b

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  5 in total

Review 1.  Aryl Transfer Strategies Mediated by Photoinduced Electron Transfer.

Authors:  Anthony R Allen; Efrey A Noten; Corey R J Stephenson
Journal:  Chem Rev       Date:  2021-10-21       Impact factor: 72.087

2.  Alkene 1,2-Difunctionalization by Radical Alkenyl Migration.

Authors:  Xinjun Tang; Armido Studer
Journal:  Angew Chem Int Ed Engl       Date:  2017-12-14       Impact factor: 15.336

3.  α-Perfluoroalkyl-β-alkynylation of alkenes via radical alkynyl migration.

Authors:  Xinjun Tang; Armido Studer
Journal:  Chem Sci       Date:  2017-08-04       Impact factor: 9.825

Review 4.  Progress in Difluoroalkylation of Organic Substrates by Visible Light Photoredox Catalysis.

Authors:  Agostinho Lemos; Christian Lemaire; André Luxen
Journal:  Adv Synth Catal       Date:  2019-01-17       Impact factor: 5.837

Review 5.  Difunctionalization of Alkenes and Alkynes via Intermolecular Radical and Nucleophilic Additions.

Authors:  Hongjun Yao; Wenfei Hu; Wei Zhang
Journal:  Molecules       Date:  2020-12-28       Impact factor: 4.411
  5 in total

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