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Literature DB >> 25811751

Self-assembly of an unprecedented polyoxomolybdate anion [Mo20O66]12- in a giant peanut-like 62-core silver-thiolate nanocluster.

Ren-Wu Huang¹, Qing-Qing Xu, Hong-Lin Lu, Xiao-Kang Guo, Shuang-Quan Zang, Guang-Gang Gao, Ming-Sheng Tang, Thomas C W Mak.

Abstract

A polyoxometalate-templated silver thiolate nanocluster, [Ag62(S(t)Bu)40(Mo20O66)(Mo6O19)3(CH3CN)2]·(CF3SO3)4 (1), has been isolated, in which a giant peanut-like silver(i)-thiolate cluster [Ag62(S(t)Bu)40](22+) encapsulates an unprecedented [Mo20O66](12-) polyoxoanion core. It opens a new approach for the synthesis of both elusive polyoxometalates and high-nuclearity silver(i)-thiolate nanoclusters.

Entities: Chemical Species

Year: 2015 PMID： 25811751 DOI： 10.1039/c5nr00171d

Source DB: PubMed Journal: Nanoscale ISSN： 2040-3364 Impact factor: 7.790

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Cited

5 in total

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Authors: Yan-Min Su; Zhi Wang; Gui-Lin Zhuang; Quan-Qin Zhao; Xing-Po Wang; Chen-Ho Tung; Di Sun
Journal: Chem Sci Date: 2018-10-18 Impact factor: 9.825

4. [Ag₉(1,2-BDT)₆]^3-: How Square-Pyramidal Building Blocks Self-Assemble into the Smallest Silver Nanocluster.

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5. Core-dependent properties of copper nanoclusters: valence-pure nanoclusters as NIR TADF emitters and mixed-valence ones as semiconductors.

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Journal: Chem Sci Date: 2019-09-07 Impact factor: 9.825

5 in total

Self-assembly of an unprecedented polyoxomolybdate anion [Mo20O66]12- in a giant peanut-like 62-core silver-thiolate nanocluster.

1. Trapping an octahedral Ag6 kernel in a seven-fold symmetric Ag56 nanowheel.

2. Carboxylic acid stimulated silver shell isomerism in a triple core-shell Ag84 nanocluster.

3. Unusual fcc-structured Ag10 kernels trapped in Ag70 nanoclusters.

4. [Ag9(1,2-BDT)6]3-: How Square-Pyramidal Building Blocks Self-Assemble into the Smallest Silver Nanocluster.

5. Core-dependent properties of copper nanoclusters: valence-pure nanoclusters as NIR TADF emitters and mixed-valence ones as semiconductors.

1. Trapping an octahedral Ag₆ kernel in a seven-fold symmetric Ag₅₆ nanowheel.

2. Carboxylic acid stimulated silver shell isomerism in a triple core-shell Ag₈₄ nanocluster.

3. Unusual fcc-structured Ag₁₀ kernels trapped in Ag₇₀ nanoclusters.

4. [Ag₉(1,2-BDT)₆]^3-: How Square-Pyramidal Building Blocks Self-Assemble into the Smallest Silver Nanocluster.