Literature DB >> 25797146

B(C6F5)3 mediated arene hydrogenation/transannulation of para-methoxyanilines.

Lauren E Longobardi1, Tayseer Mahdi, Douglas W Stephan.   

Abstract

The stoichiometric reaction of para-methoxyanilines and B(C6F5)3 under H2 results in reduction of the N-bound phenyl ring(s), and subsequent transannular ring closure with elimination of methanol, affording the respective 7-azabicyclo[2.2.1]heptane derivatives.

Entities:  

Year:  2015        PMID: 25797146     DOI: 10.1039/c5dt00921a

Source DB:  PubMed          Journal:  Dalton Trans        ISSN: 1477-9226            Impact factor:   4.390


  2 in total

1.  The 7-aza-norbornane nucleus of epibatidine: 7-aza-bicyclo-[2.2.1]heptan-7-ium chloride.

Authors:  Sergey N Britvin; Andrey M Rumyantsev
Journal:  Acta Crystallogr E Crystallogr Commun       Date:  2017-08-30

2.  Heterolytic Splitting of Molecular Hydrogen by Frustrated and Classical Lewis Pairs: A Unified Reactivity Concept.

Authors:  Gabriella Skara; Freija De Vleeschouwer; Paul Geerlings; Frank De Proft; Balazs Pinter
Journal:  Sci Rep       Date:  2017-11-22       Impact factor: 4.379

  2 in total

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