Literature DB >> 25791698

Two-coordinate hydrido-germylenes.

Terrance J Hadlington1, Benedikt Schwarze, Ekaterina I Izgorodina, Cameron Jones.   

Abstract

The first structurally characterised two-coordinate hydrido-germylenes, :Ge(H)L (L = -N(Ar){Si(OBu)}, Ar = C6H2{C(H)Ph2}2R-2,6,4; R = Pr(i) ((tBuO)L(†)), Me ((tBuO)L*)), have been prepared, and their dimerisation shown to be thermodynamically unfavourable, largely due to the extreme steric bulk of their amide ligands.

Entities:  

Year:  2015        PMID： 25791698     DOI： 10.1039/c5cc01314c

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  2 in total

1.  Geometrically Constrained Cationic Low-Coordinate Tetrylenes: Highly Lewis Acidic σ-Donor Ligands in Catalytic Systems.

Authors:  Philip M Keil; Terrance J Hadlington
Journal:  Angew Chem Int Ed Engl       Date:  2022-01-11       Impact factor: 16.823

2.  Molecular Ln(III)-H-E(II) Linkages (Ln=Y, Lu; E=Ge, Sn, Pb).

Authors:  Max Widemann; Frederik S W Aicher; Martin Bonath; Klaus Eichele; Cäcilia Maichle-Mössmer; Hartmut Schubert; Peter Sirsch; Reiner Anwander; Lars Wesemann
Journal:  Chemistry       Date:  2022-06-23       Impact factor: 5.020
  2 in total

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