Literature DB >> 25789721

Alkali metal-mediated dehydrocoupling of Me2NH·BH3.

Peter Bellham1, Michael S Hill, Gabriele Kociok-Köhn.   

Abstract

Bis(trimethylsilyl)amide derivatives of the group 1 elements (Li, Na, K) are competent pre-catalysts for the dehydrocoupling of Me2NH·BH3 via the formation of intermediates containing [H3BNMe2BH2Me2N](-) anions.

Entities:  

Year:  2015        PMID： 25789721     DOI： 10.1039/c5dt00178a

Source DB:  PubMed          Journal:  Dalton Trans        ISSN： 1477-9226            Impact factor:   4.390


  4 in total

1.  Lithium Dihydropyridine Dehydrogenation Catalysis: A Group 1 Approach to the Cyclization of Diamine Boranes.

Authors:  Ross McLellan; Alan R Kennedy; Samantha A Orr; Stuart D Robertson; Robert E Mulvey
Journal:  Angew Chem Int Ed Engl       Date:  2016-12-21       Impact factor: 15.336

2.  1-Alkali-metal-2-alkyl-1,2-dihydropyridines: Soluble Hydride Surrogates for Catalytic Dehydrogenative Coupling and Hydroboration Applications.

Authors:  Ross McLellan; Alan R Kennedy; Robert E Mulvey; Samantha A Orr; Stuart D Robertson
Journal:  Chemistry       Date:  2017-11-03       Impact factor: 5.236

3.  A Highly Active Bidentate Magnesium Catalyst for Amine-Borane Dehydrocoupling: Kinetic and Mechanistic Studies.

Authors:  Alexander C A Ried; Laurence J Taylor; Ana M Geer; Huw E L Williams; William Lewis; Alexander J Blake; Deborah L Kays
Journal:  Chemistry       Date:  2019-04-25       Impact factor: 5.236

4.  Homo- and heterodehydrocoupling of phosphines mediated by alkali metal catalysts.

Authors:  Lipeng Wu; Vincent T Annibale; Haijun Jiao; Adam Brookfield; David Collison; Ian Manners
Journal:  Nat Commun       Date:  2019-06-26       Impact factor: 14.919
  4 in total

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