| Literature DB >> 25783694 |
Tsumoru Morimoto1, Tetsuji Fujii, Kota Miyoshi, Gouki Makado, Hiroki Tanimoto, Yasuhiro Nishiyama, Kiyomi Kakiuchi.
Abstract
We report herein on an accessible protocol for the asymmetric hydroformylation of vinylarenes using formaldehyde as a substitute for syngas. The regioselectivity (branched/linear = up to 96/4) and enantioselectivity (up to 95% ee) can be attributed to the use of chiral Ph-bpe as a ligand.Entities:
Year: 2015 PMID： 25783694 DOI： 10.1039/c5ob00378d
Source DB: PubMed Journal: Org Biomol Chem ISSN： 1477-0520 Impact factor: 3.876