Literature DB >> 25772087

Visible light photooxidation of nitrate: the dawn of a nocturnal radical.

T Hering1, T Slanina, A Hancock, U Wille, B König.   

Abstract

Highly oxidizing nitrate radicals (NO3˙) are easily accessed from readily available nitrate salts by visible light photoredox catalysis using a purely organic dye as the catalyst and oxygen as the terminal oxidant. The interaction of the excited catalyst and nitrate anions was studied by spectroscopic methods to elucidate the mechanism, and the method was applied to the NO3˙ induced oxidation of alkynes and alcohols.

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Year:  2015        PMID: 25772087     DOI: 10.1039/c5cc01580d

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  4 in total

1.  Homobenzylic Oxygenation Enabled by Dual Organic Photoredox and Cobalt Catalysis.

Authors:  Joshua B McManus; Jeremy D Griffin; Alexander R White; David A Nicewicz
Journal:  J Am Chem Soc       Date:  2020-06-02       Impact factor: 15.419

2.  β-Functionalization of Saturated Aza-Heterocycles Enabled by Organic Photoredox Catalysis.

Authors:  Natalie Holmberg-Douglas; Younggi Choi; Brian Aquila; Hoan Huynh; David A Nicewicz
Journal:  ACS Catal       Date:  2021-02-24       Impact factor: 13.700

Review 3.  Electrochemistry and Photoredox Catalysis: A Comparative Evaluation in Organic Synthesis.

Authors:  Rik H Verschueren; Wim M De Borggraeve
Journal:  Molecules       Date:  2019-06-05       Impact factor: 4.411

4.  Efficient Syntheses of Biobased Terephthalic Acid, p-Toluic Acid, and p-Methylacetophenone via One-Pot Catalytic Aerobic Oxidation of Monoterpene Derived Bio-p-cymene.

Authors:  Joshua D Tibbetts; Danilo Russo; Alexei A Lapkin; Steven D Bull
Journal:  ACS Sustain Chem Eng       Date:  2021-06-17       Impact factor: 8.198

  4 in total

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