| Literature DB >> 25765939 |
Renhong Sun1, Jun Liu, Shuang Yang, Ming Chen, Ning Sun, Haoyi Chen, Xin Xie, Xu You, Shi Li, Yuanhong Liu.
Abstract
A titanium-catalyzed cis-hydroalumination of propargylic amines with Red-Al is described, which provides an efficient way to produce Z-configured allylic amines in good to excellent yields with high stereoselectivity and good regioselectivity. The hydride-bridged Al/Ti bimetallic species may act as a real catalyst in this reaction.Entities:
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Year: 2015 PMID： 25765939 DOI： 10.1039/c5cc00950b
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222