Literature DB >> 25759865

Deprotonation of a dinuclear copper complex of 3,5-diamino-1,2,4-triazole for high oxygen reduction activity.

Masaru Kato1, Ken'ichi Kimijima, Mari Shibata, Hideo Notsu, Kazuya Ogino, Kiyoshi Inokuma, Narumi Ohta, Hiromitsu Uehara, Yohei Uemura, Nobuhisa Oyaizu, Tadashi Ohba, Satoru Takakusagi, Kiyotaka Asakura, Ichizo Yagi.   

Abstract

A dinuclear copper(II) complex of 3,5-diamino-1,2,4-triazole is one of the highly active copper-based catalysts for the oxygen reduction reaction (ORR) in basic solutions. Our in situ X-ray absorption near edge structure measurements revealed that deprotonation of the triazole ligand might cause coordination geometrical changes, resulting in the enhancement of the ORR activity.

Entities:  

Year:  2015        PMID: 25759865     DOI: 10.1039/c4cp05595k

Source DB:  PubMed          Journal:  Phys Chem Chem Phys        ISSN: 1463-9076            Impact factor:   3.676


  3 in total

1.  A dinuclear cobalt cluster as electrocatalyst for oxygen reduction reaction.

Authors:  Yun-Wu Li; Wen-Jie Zhang; Chun-Xia Li; Lin Gu; Hong-Mei Du; Hui-Yan Ma; Su-Na Wang; Jin-Sheng Zhao
Journal:  RSC Adv       Date:  2019-12-23       Impact factor: 3.361

2.  A cobalt-pyrrole coordination compound as high performance cathode catalyst for direct borohydride fuel cells.

Authors:  Yuehan Chen; Shuping Wang; Zhoupeng Li
Journal:  RSC Adv       Date:  2020-08-06       Impact factor: 4.036

3.  Pinpointing the active species of the Cu(DAT) catalyzed oxygen reduction reaction.

Authors:  Bas van Dijk; Jan P Hofmann; Dennis G H Hetterscheid
Journal:  Phys Chem Chem Phys       Date:  2018-07-25       Impact factor: 3.676

  3 in total

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