Literature DB >> 25748071

Oxidative cleavage of allyl ethers by an oxoammonium salt.

Christopher B Kelly1, John M Ovian, Robin M Cywar, Taylor R Gosselin, Rebecca J Wiles, Nicholas E Leadbeater.   

Abstract

A method to oxidatively cleave allyl ethers to their corresponding aldehydes mediated by an oxoammonium salt is described. Using a biphasic solvent system and mild heating, cleavage proceeds readily, furnishing a variety of α,β-unsaturated aldehydes and ketones.

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Year:  2015        PMID: 25748071     DOI: 10.1039/c5ob00270b

Source DB:  PubMed          Journal:  Org Biomol Chem        ISSN: 1477-0520            Impact factor:   3.876


  2 in total

1.  Oxidation of Secondary Methyl Ethers to Ketones.

Authors:  Pieter J Gilissen; Daniel Blanco-Ania; Floris P J T Rutjes
Journal:  J Org Chem       Date:  2017-06-12       Impact factor: 4.354

2.  Iodine/water-mediated deprotective oxidation of allylic ethers to access α,β-unsaturated ketones and aldehydes.

Authors:  Yuntian Xue; Yaolong Yan; Kezhi Jiang; Weifeng Chen; Lei Yang
Journal:  RSC Adv       Date:  2020-04-14       Impact factor: 3.361

  2 in total

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