Literature DB >> 25747898

Reductive cleavage of P4 by iron(I) centres: synthesis and structural characterisation of Fe2(P2)2 complexes with two bridging P2(2-) ligands.

Shenglai Yao1, Tibor Szilvási, Nils Lindenmaier, Yun Xiong, Shigeyoshi Inoue, Mario Adelhardt, Jörg Sutter, Karsten Meyer, Matthias Driess.   

Abstract

The selective transformation of white phosphorus with a β-diketiminato iron(I) toluene complex under mild reaction conditions is reported which furnishes a new dinuclear iron(III) Fe2(P2)2 complex with two bridging P2(2-) ligands. Its reduction with potassium results in the formation of the first delocalised mixed-valent bis-diphosphido iron(II,III) complex which is isostructural with the neutral Fe2P4 precursor.

Entities:  

Year:  2015        PMID： 25747898     DOI： 10.1039/c5cc00147a

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  8 in total

1.  A New Domain of Reactivity for High-Valent Dinuclear [M(μ-O)2 M'] Complexes in Oxidation Reactions.

Authors:  Xenia Engelmann; Shenglai Yao; Erik R Farquhar; Tibor Szilvási; Uwe Kuhlmann; Peter Hildebrandt; Matthias Driess; Kallol Ray
Journal:  Angew Chem Int Ed Engl       Date:  2016-12-01       Impact factor: 15.336

2.  Conversion of E4 (E4 =P4 , As4 , AsP3 ) by Ni(0) and Ni(I) Synthons - A Comparative Study.

Authors:  Maria Haimerl; Christian Graßl; Michael Seidl; Martin Piesch; Manfred Scheer
Journal:  Chemistry       Date:  2021-11-23       Impact factor: 5.020

3.  Influence of the nacnac Ligand in Iron(I)-Mediated P4 Transformations.

Authors:  Fabian Spitzer; Christian Graßl; Gábor Balázs; Eva M Zolnhofer; Karsten Meyer; Manfred Scheer
Journal:  Angew Chem Int Ed Engl       Date:  2016-02-29       Impact factor: 15.336

4.  Metalate-Mediated Functionalization of P4 by Trapping Anionic [Cp*Fe(CO)2(η1-P4)]- with Lewis Acids.

Authors:  Jaap E Borger; Maarten K Jongkind; Andreas W Ehlers; Martin Lutz; J Chris Slootweg; Koop Lammertsma
Journal:  ChemistryOpen       Date:  2017-03-23       Impact factor: 2.911

5.  Nacnac-Cobalt-Mediated P4 Transformations.

Authors:  Fabian Spitzer; Christian Graßl; Gábor Balázs; Eric Mädl; Martin Keilwerth; Eva M Zolnhofer; Karsten Meyer; Manfred Scheer
Journal:  Chemistry       Date:  2017-01-25       Impact factor: 5.236

6.  From an Fe2P3 complex to FeP nanoparticles as efficient electrocatalysts for water-splitting.

Authors:  Shenglai Yao; Viktoria Forstner; Prashanth W Menezes; Chakadola Panda; Stefan Mebs; Eva M Zolnhofer; Matthias E Miehlich; Tibor Szilvási; Nanjundan Ashok Kumar; Michael Haumann; Karsten Meyer; Hansjörg Grützmacher; Matthias Driess
Journal:  Chem Sci       Date:  2018-09-17       Impact factor: 9.825

Review 7.  A μ-Phosphido Diiron Dumbbell in Multiple Oxidation States.

Authors:  Munmun Ghosh; Hanna H Cramer; Sebastian Dechert; Serhiy Demeshko; Michael John; Max M Hansmann; Shengfa Ye; Franc Meyer
Journal:  Angew Chem Int Ed Engl       Date:  2019-08-23       Impact factor: 15.336

Review 8.  Functionalization of Pentaphosphorus Cations by Complexation.

Authors:  Anup K Adhikari; Christoph G P Ziegler; Kai Schwedtmann; Clemens Taube; Jan J Weigand; Robert Wolf
Journal:  Angew Chem Int Ed Engl       Date:  2019-11-06       Impact factor: 15.336
  8 in total

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