Literature DB >> 25741992

Chemoselective hydrogenation of carbonyl compounds and acceptorless dehydrogenative coupling of alcohols.

Denis Spasyuk1, Cristian Vicent2, Dmitry G Gusev1.   

Abstract

OsHCl(CO)[κ(3)-PyCH2NHC2H4NHPtBu2] is the first efficient catalyst for chemoselective reduction of challenging unsaturated esters to enols and for acceptorless coupling of amines with MeOH and EtOH affording formamides and acetamides. The NMR, ESI-MS, and DFT data indicate a mechanism proceeding in the metal coordination sphere and producing no free organic intermediates.

Entities:  

Year:  2015        PMID： 25741992     DOI： 10.1021/ja512389y

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  11 in total

1.  Basic Promotors Impact Thermodynamics and Catalyst Speciation in Homogeneous Carbonyl Hydrogenation.

Authors:  Wenjun Yang; Tejas Y Kalavalapalli; Annika M Krieger; Taras A Khvorost; Ivan Yu Chernyshov; Manuela Weber; Evgeny A Uslamin; Evgeny A Pidko; Georgy A Filonenko
Journal:  J Am Chem Soc       Date:  2022-04-27       Impact factor: 16.383

2.  Silyl formates as hydrosilane surrogates for the transfer hydrosilylation of ketones.

Authors:  R Martin Romero; Neethu Thyagarajan; Nora Hellou; Clément Chauvier; Timothé Godou; Lucile Anthore-Dalion; Thibault Cantat
Journal:  Chem Commun (Camb)       Date:  2022-05-26       Impact factor: 6.065

3.  CH2 Linkage Effects on the Reactivity of Bis(aminophosphine)-Ruthenium Complexes for Selective Hydrogenation of Esters into Alcohols.

Authors:  Xiaolong Fang; Mingjun Sun; Jianwei Zheng; Bin Li; Linmin Ye; Xiaoping Wang; Zexing Cao; Hongping Zhu; Youzhu Yuan
Journal:  Sci Rep       Date:  2017-06-21       Impact factor: 4.379

4.  Efficient and selective hydrogenation of amides to alcohols and amines using a well-defined manganese-PNN pincer complex.

Authors:  Veronica Papa; Jose R Cabrero-Antonino; Elisabetta Alberico; Anke Spanneberg; Kathrin Junge; Henrik Junge; Matthias Beller
Journal:  Chem Sci       Date:  2017-03-08       Impact factor: 9.825

5.  Chemoselective dehydrogenative esterification of aldehydes and alcohols with a dimeric rhodium(ii) catalyst.

Authors:  Junjie Cheng; Meijuan Zhu; Chao Wang; Junjun Li; Xue Jiang; Yawen Wei; Weijun Tang; Dong Xue; Jianliang Xiao
Journal:  Chem Sci       Date:  2016-03-29       Impact factor: 9.825

6.  Enhanced Catalytic Activity of Nickel Complexes of an Adaptive Diphosphine-Benzophenone Ligand in Alkyne Cyclotrimerization.

Authors:  Alessio F Orsino; Manuel Gutiérrez Del Campo; Martin Lutz; Marc-Etienne Moret
Journal:  ACS Catal       Date:  2019-01-31       Impact factor: 13.084

7.  Additive-Mediated Selective Oxidation of Alcohols to Esters via Synergistic Effect Using Single Cation Cobalt Catalyst Stabilized with Inorganic Ligand.

Authors:  Jingjing Wang; Han Yu; Zheyu Wei; Qi Li; Weimin Xuan; Yongge Wei
Journal:  Research (Wash D C)       Date:  2020-01-23

8.  The key role of the latent N-H group in Milstein's catalyst for ester hydrogenation.

Authors:  John Pham; Cole E Jarczyk; Eamon F Reynolds; Sophie E Kelly; Thao Kim; Tianyi He; Jason M Keith; Anthony R Chianese
Journal:  Chem Sci       Date:  2021-05-24       Impact factor: 9.825

9.  Acceptorless dehydrogenative synthesis of primary amides from alcohols and ammonia.

Authors:  Jie Luo; Quan-Quan Zhou; Michael Montag; Yehoshoa Ben-David; David Milstein
Journal:  Chem Sci       Date:  2022-03-02       Impact factor: 9.825

10.  Hydration of Aliphatic Nitriles Catalyzed by an Osmium Polyhydride: Evidence for an Alternative Mechanism.

Authors:  Juan C Babón; Miguel A Esteruelas; Ana M López; Enrique Oñate
Journal:  Inorg Chem       Date:  2021-04-27       Impact factor: 5.165
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