Literature DB >> 25737368

Recent developments in the trifluoromethylation of alkynes.

Pin Gao1, Xian-Rong Song, Xue-Yuan Liu, Yong-Min Liang.   

Abstract

In the last few years, the development of versatile methodologies to incorporate trifluoromethyl groups into organic molecules has attracted significant attention in synthetic chemistry. This review gives an overview over the development on the trifluoromethylation of alkynes, which have not been solely discussed before. Formation of diverse C(sp, sp(2) , sp(3) )-CF3 bonds are all covered in this review.
© 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  alkyne; difunctionalization; radical reactions; synthetic methods; trifluoromethylation

Mesh：

Substances：

Year:  2015        PMID： 25737368     DOI： 10.1002/chem.201406432

Source DB:  PubMed          Journal:  Chemistry        ISSN： 0947-6539            Impact factor:   5.236


  10 in total

Review 1.  Progress in copper-catalyzed trifluoromethylation.

Authors:  Guan-Bao Li; Chao Zhang; Chun Song; Yu-Dao Ma
Journal:  Beilstein J Org Chem       Date:  2018-01-17       Impact factor: 2.883

2.  Stereoselective cobalt-catalyzed halofluoroalkylation of alkynes.

Authors:  Guojiao Wu; Axel Jacobi von Wangelin
Journal:  Chem Sci       Date:  2018-01-05       Impact factor: 9.825

Review 3.  Vicinal halo-trifluoromethylation of alkenes.

Authors:  Rzgar Tawfeeq Kareem; Bayan Azizi; Manzarbanou Asnaashariisfahani; Abdolghaffar Ebadi; Esmail Vessally
Journal:  RSC Adv       Date:  2021-04-21       Impact factor: 3.361

Review 4.  Recent trends in dehydroxylative trifluoro-methylation, -methoxylation, -methylthiolation, and -methylselenylation of alcohols.

Authors:  Yan Cao; Roya Ahmadi; Mohammad Reza Poor Heravi; Alibek Issakhov; Abdol Ghaffar Ebadi; Esmail Vessally
Journal:  RSC Adv       Date:  2021-12-13       Impact factor: 4.036

5.  Oxydifluoromethylation of Alkenes by Photoredox Catalysis: Simple Synthesis of CF2H-Containing Alcohols.

Authors:  Yusuke Arai; Ren Tomita; Gaku Ando; Takashi Koike; Munetaka Akita
Journal:  Chemistry       Date:  2015-12-16       Impact factor: 5.236

6.  A remote C-C bond cleavage-enabled skeletal reorganization: Access to medium-/large-sized cyclic alkenes.

Authors:  Lei Li; Zhong-Liang Li; Qiang-Shuai Gu; Na Wang; Xin-Yuan Liu
Journal:  Sci Adv       Date:  2017-11-03       Impact factor: 14.136

7.  Redox-ligand sustains controlled generation of CF3 radicals by well-defined copper complex.

Authors:  Jérémy Jacquet; Sébastien Blanchard; Etienne Derat; Marine Desage-El Murr; Louis Fensterbank
Journal:  Chem Sci       Date:  2015-12-03       Impact factor: 9.825

8.  Successive C-C bond cleavage, fluorination, trifluoromethylthio- and pentafluorophenylthiolation under metal-free conditions to provide compounds with dual fluoro-functionalization.

Authors:  Ibrayim Saidalimu; Shugo Suzuki; Etsuko Tokunaga; Norio Shibata
Journal:  Chem Sci       Date:  2015-12-09       Impact factor: 9.825

9.  Synthesis of difluoromethylated allenes through trifunctionalization of 1,3-enynes.

Authors:  Munira Taj Muhammad; Yihang Jiao; Changqing Ye; Mong-Feng Chiou; Muhammad Israr; Xiaotao Zhu; Yajun Li; Zhenhai Wen; Armido Studer; Hongli Bao
Journal:  Nat Commun       Date:  2020-01-21       Impact factor: 14.919

10.  Phosphine-Free Ru-Catalyzed Regio- and Stereoselective Addition of Benzoic Acids to Trifluoromethylated Alkynes toward Facile Access to Trifluoromethyl Group-Substituted (E)-Enol Esters.

Authors:  Guangyuan Liu; Xingxing Zhang; Guanghua Kuang; Naihao Lu; Yang Fu; Yiyuan Peng; Qiang Xiao; Yirong Zhou
Journal:  ACS Omega       Date:  2020-02-20
  10 in total

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