Literature DB >> 25734856

Structure determination and modeling of monoclinic trioctylphosphine oxide.

Vicky V T Doan-Nguyen1, Patrick J Carroll2, Christopher B Murray1.   

Abstract

Trioctylphosphine oxide (TOPO), C(24)H(51)OP, was recrystallized from ambient evaporation in acetone. TOPO single crystals form with a monoclinic P2(1)/c structure. Fourier transform IR (FT-IR) spectroscopy captures the characteristic stretching modes from the seven methylene groups, the phosphoryl P=O bond, and the phosphoryl-carbon bond.

Entities:  

Keywords:  TOPO; crystal structure; ligand stabilizer; nanocrystal synthesis; phosphorus source; trioctylphosphine oxide

Year:  2015        PMID: 25734856     DOI: 10.1107/S2053229615003009

Source DB:  PubMed          Journal:  Acta Crystallogr C Struct Chem        ISSN: 2053-2296            Impact factor:   1.172


  1 in total

1.  Calcination does not remove all carbon from colloidal nanocrystal assemblies.

Authors:  Pratyasha Mohapatra; Santosh Shaw; Deyny Mendivelso-Perez; Jonathan M Bobbitt; Tiago F Silva; Fabian Naab; Bin Yuan; Xinchun Tian; Emily A Smith; Ludovico Cademartiri
Journal:  Nat Commun       Date:  2017-12-11       Impact factor: 14.919

  1 in total

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