Literature DB >> 25728494

Direct allylation of quinones with allylboronates.

Hong-Ping Deng1, Dong Wang1, Kálmán J Szabó1.   

Abstract

Allylboronates undergo C-H allylation of unsubstituted or monosubstituted benzoquinone and naphthoquinone substrates. In the case of 2,5- or 2,6-disubstituted quinones addition involving the substituted carbon takes place. Allylation with stereodefined allylboronates occurs with retention of the configuration.

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Year:  2015        PMID: 25728494     DOI: 10.1021/acs.joc.5b00264

Source DB:  PubMed          Journal:  J Org Chem        ISSN: 0022-3263            Impact factor:   4.354


  3 in total

1.  Metal-Free Aminohalogenation of Quinones With Alkylamines and NXS at Room Temperature.

Authors:  Jia Li; Yu-An Li; Ge Wu; Xu Zhang
Journal:  Front Chem       Date:  2022-05-20       Impact factor: 5.545

2.  Propargylation of CoQ0 through the Redox Chain Reaction.

Authors:  Robert Pawlowski; Maciej Stodulski; Jacek Mlynarski
Journal:  J Org Chem       Date:  2021-12-21       Impact factor: 4.354

3.  Introducing unactivated acyclic internal aliphatic olefins into a cobalt catalyzed allylic selective dehydrogenative Heck reaction.

Authors:  Soham Maity; Pravas Dolui; Rajesh Kancherla; Debabrata Maiti
Journal:  Chem Sci       Date:  2017-05-16       Impact factor: 9.825

  3 in total

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