| Literature DB >> 25728054 |
Bartosz Szyszko1, Agata Białońska, Ludmiła Szterenberg, Lechosław Latos-Grażyński.
Abstract
The incorporation of a phenanthrene moiety into a porphyrin framework results in the formation of a hybrid macrocycle—phenanthriporphyrin—merging the structural features of polycyclic aromatic hydrocarbons and porphyrins. An antiaromatic aceneporphyrinoid, adopting the trianionic {CCNN} core, is suitable for the incorporation of a phosphorus(V) center to form a hypervalent organophosphorus(V) derivative.Entities:
Keywords: antiaromaticity; conjugation; phenanthrene; phosphorus; porphyrinoids
Year: 2015 PMID： 25728054 DOI： 10.1002/anie.201500732
Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336