Literature DB >> 25727341

Effective separation of the actinides Am(III) and Cm(III) by electronic modulation of bis-(1,2,4-triazin-3-yl)phenanthrolines.

Ashfaq Afsar1, Laurence M Harwood, Michael J Hudson, James Westwood, Andreas Geist.   

Abstract

It has been shown that modification of the phenanthroline backbone of CyMe4-BTPhen leads to subtle electronic modulation, permitting differential ligation of Am(III) and Cm(III) resulting in separation factors up to 7.

Entities:  

Year:  2015        PMID： 25727341     DOI： 10.1039/c5cc00567a

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  2 in total

1.  Exploring the Subtle Effect of Aliphatic Ring Size on Minor Actinide-Extraction Properties and Metal Ion Speciation in Bis-1,2,4-Triazine Ligands.

Authors:  Andrey V Zaytsev; Rachel Bulmer; Valery N Kozhevnikov; Mark Sims; Giuseppe Modolo; Andreas Wilden; Paul G Waddell; Andreas Geist; Petra J Panak; Patrik Wessling; Frank W Lewis
Journal:  Chemistry       Date:  2019-10-30       Impact factor: 5.236

2.  Influence of Electronic Modulation of Phenanthroline-Derived Ligands on Separation of Lanthanides and Actinides.

Authors:  Ming-Ming Li; Xiao-Juan Liu; Qi Yang; Yue-Kun Liu; Jiang Nie; Shu-Ming Yang; Ya-Ya Yang; Fu-Yan Lou; Song-Tao Xiao; Ying-Gen Ouyang; Guo-An Ye
Journal:  Molecules       Date:  2022-03-09       Impact factor: 4.411
  2 in total

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