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Literature DB >> 25722647

Experimental Evidence of Negative Linear Compressibility in the MIL-53 Metal-Organic Framework Family.

Pablo Serra-Crespo¹, Alla Dikhtiarenko¹, Eli Stavitski², Jana Juan-Alcañiz¹, Freek Kapteijn¹, François-Xavier Coudert³, Jorge Gascon¹.

Abstract

We report a series of powder X-ray diffraction experiments performed on the soft porous crystals MIL-53(Al) and NH2-MIL-53(Al) in a diamond anvil cell under different pressurization media. Systematic refinements of the obtained powder patterns demonstrate that these materials expand along a specific direction while undergoing total volume reduction under an increase in hydrostatic pressure. The results confirm for the first time the Negative Linear Compressibility behaviour of this family of materials recently predicted from quantum chemical calculations.

Entities: Chemical

Year: 2015 PMID： 25722647 PMCID： PMC4338503 DOI： 10.1039/C4CE00436A

Source DB: PubMed Journal: CrystEngComm ISSN： 1466-8033 Impact factor: 3.545

29 in total

1. High-pressure crystallography.

Authors: Andrzej Katrusiak
Journal: Acta Crystallogr A Date: 2007-12-21 Impact factor: 2.290

2. Guest-dependent high pressure phenomena in a nanoporous metal-organic framework material.

Authors: Karena W Chapman; Gregory J Halder; Peter J Chupas
Journal: J Am Chem Soc Date: 2008-07-18 Impact factor: 15.419

3. Metal-organic frameworks with wine-rack motif: what determines their flexibility and elastic properties?

Authors: Aurélie U Ortiz; A Boutin; Alain H Fuchs; François-Xavier Coudert
Journal: J Chem Phys Date: 2013-05-07 Impact factor: 3.488

4. Rational design of materials with extreme negative compressibility: selective soft-mode frustration in KMn[Ag(CN)2]3.

Authors: Andrew B Cairns; Amber L Thompson; Matthew G Tucker; Julien Haines; Andrew L Goodwin
Journal: J Am Chem Soc Date: 2011-07-27 Impact factor: 15.419

5. Adsorption and separation of light gases on an amino-functionalized metal-organic framework: an adsorption and in situ XRD study.

Authors: Sarah Couck; Elena Gobechiya; Christine E A Kirschhock; Pablo Serra-Crespo; Jana Juan-Alcañiz; Alberto Martinez Joaristi; Eli Stavitski; Jorge Gascon; Freek Kapteijn; Gino V Baron; Joeri F M Denayer
Journal: ChemSusChem Date: 2012-02-29 Impact factor: 8.928

6. Structural transitions in MIL-53 (Cr): view from outside and inside.

Authors: Alexander V Neimark; François-Xavier Coudert; Carles Triguero; Anne Boutin; Alain H Fuchs; Isabelle Beurroies; Renaud Denoyel
Journal: Langmuir Date: 2011-03-18 Impact factor: 3.882

7. Interplay of metal node and amine functionality in NH2-MIL-53: modulating breathing behavior through intra-framework interactions.

Authors: Pablo Serra-Crespo; Elena Gobechiya; Enrique V Ramos-Fernandez; Jana Juan-Alcañiz; Alberto Martinez-Joaristi; Eli Stavitski; Christine E A Kirschhock; Johan A Martens; Freek Kapteijn; Jorge Gascon
Journal: Langmuir Date: 2012-08-23 Impact factor: 3.882

8. Giant negative linear compressibility in zinc dicyanoaurate.

Authors: Andrew B Cairns; Jadna Catafesta; Claire Levelut; Jérôme Rouquette; Arie van der Lee; Lars Peters; Amber L Thompson; Vladimir Dmitriev; Julien Haines; Andrew L Goodwin
Journal: Nat Mater Date: 2013-01-20 Impact factor: 43.841

9. Pressure-induced amorphization and porosity modification in a metal-organic framework.

Authors: Karena W Chapman; Gregory J Halder; Peter J Chupas
Journal: J Am Chem Soc Date: 2009-12-09 Impact factor: 15.419

10. Pressure-induced cooperative bond rearrangement in a zinc imidazolate framework: a high-pressure single-crystal X-ray diffraction study.

Authors: Elinor C Spencer; Ross J Angel; Nancy L Ross; Brian E Hanson; Judith A K Howard
Journal: J Am Chem Soc Date: 2009-03-25 Impact factor: 15.419

9 in total

Experimental Evidence of Negative Linear Compressibility in the MIL-53 Metal-Organic Framework Family.

1. High-pressure crystallography.

2. Guest-dependent high pressure phenomena in a nanoporous metal-organic framework material.

3. Metal-organic frameworks with wine-rack motif: what determines their flexibility and elastic properties?

4. Rational design of materials with extreme negative compressibility: selective soft-mode frustration in KMn[Ag(CN)2]3.

5. Adsorption and separation of light gases on an amino-functionalized metal-organic framework: an adsorption and in situ XRD study.

6. Structural transitions in MIL-53 (Cr): view from outside and inside.

7. Interplay of metal node and amine functionality in NH2-MIL-53: modulating breathing behavior through intra-framework interactions.

8. Giant negative linear compressibility in zinc dicyanoaurate.

9. Pressure-induced amorphization and porosity modification in a metal-organic framework.

10. Pressure-induced cooperative bond rearrangement in a zinc imidazolate framework: a high-pressure single-crystal X-ray diffraction study.

1. Extreme compressibility in LnFe(CN)6 coordination framework materials via molecular gears and torsion springs.

2. Thermodynamics of the Flexible Metal-Organic Framework Material MIL-53(Cr) From First Principles.

3. Can C_P Be Less Than C_V ?

4. Chemically driven negative linear compressibility in sodium amidoborane, Na(NH2BH3).

5. Pore closure in zeolitic imidazolate frameworks under mechanical pressure.

6. H3O(+) tetrahedron induction in large negative linear compressibility.

7. Thermodynamic insight into stimuli-responsive behaviour of soft porous crystals.

Review 8. Metal-Organic Frameworks in Modern Physics: Highlights and Perspectives.

Review 9. Mechanical properties of metal-organic frameworks.