Literature DB >> 25719992

Regioselective iodoazidation of alkynes: synthesis of α,α-diazidoketones.

Noriko Okamoto1, Takuya Sueda, Hideki Minami, Yoshihisa Miwa, Reiko Yanada.   

Abstract

Aryl alkyl alkynes reacted with N-iodosuccinimide (NIS) and trimethylsilyl azide (TMSN3), leading to α,α-diazidoketones via the regioselective addition of IN3 to alkynes. Huisgen cyclization of α,α-diazidoketones generated bis-triazole compounds.

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Year:  2015        PMID： 25719992     DOI： 10.1021/acs.orglett.5b00395

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  2 in total

1.  Visible light-mediated photocatalytic oxidative cleavage of activated alkynes via hydroamination: a direct approach to oxamates.

Authors:  Narenderreddy Katta; Mamata Ojha; Arumugavel Murugan; Sagar Arepally; Duddu S Sharada
Journal:  RSC Adv       Date:  2020-03-27       Impact factor: 3.361

2.  Reactions of [60]fullerene with alkynes promoted by OH.

Authors:  Wei-Wei Chang; Fa-Hui He; Alberto García-Peñas; Mehdihasan I Shekh; Zong-Jun Li
Journal:  RSC Adv       Date:  2022-05-10       Impact factor: 4.036
  2 in total

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