Literature DB >> 25715060

Catalytic asymmetric dearomatizing redox cross coupling of ketones with aryl hydrazines giving 1,4-diketones.

Shenlin Huang1, Lisa Kötzner1, Chandra Kanta De1, Benjamin List1.   

Abstract

An asymmetric Brønsted acid catalyzed dearomatizing redox cross coupling reaction has been realized, in which aryl hydrazines react with ketones to deliver 1,4-diketones, bearing an all-carbon quarternary stereocenter in high enantiopurity.

Entities:  

Year:  2015        PMID： 25715060     DOI： 10.1021/ja511200j

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  9 in total

1.  Catalytic Enantioselective Synthesis of 1,4-Keto-Alkenylboronate Esters and 1,4-Dicarbonyls.

Authors:  Michael Z Liang; Simon J Meek
Journal:  Angew Chem Int Ed Engl       Date:  2019-08-23       Impact factor: 15.336

2.  Stereocontrolled Synthesis of 1,4-Dicarbonyl Compounds by Photochemical Organocatalytic Acyl Radical Addition to Enals.

Authors:  Giulio Goti; Bartosz Bieszczad; Alberto Vega-Peñaloza; Paolo Melchiorre
Journal:  Angew Chem Int Ed Engl       Date:  2018-12-20       Impact factor: 15.336

3.  Conformational Investigations in Flexible Molecules Using Orientational NMR Constraints in Combination with 3J-Couplings and NOE Distances.

Authors:  Christophe Farès; Julia B Lingnau; Cornelia Wirtz; Ulrich Sternberg
Journal:  Molecules       Date:  2019-12-03       Impact factor: 4.411

4.  Homologation of the Fischer Indolization: A Quinoline Synthesis via Homo-Diaza-Cope Rearrangement.

Authors:  Gabriela Guillermina Gerosa; Sebastian Armin Schwengers; Rajat Maji; Chandra Kanta De; Benjamin List
Journal:  Angew Chem Int Ed Engl       Date:  2020-09-07       Impact factor: 15.336

5.  TBAI-Catalyzed Oxidative Coupling of Benzyl Ketones to Synthesize 2,3-Diaryl-1,4-Diketones in Water.

Authors:  Lingkai Kong; Xueping Hu; Li-Ping Bai
Journal:  ACS Omega       Date:  2022-01-07

6.  Divergent synthesis of benzazepines and bridged polycycloalkanones via dearomative rearrangement.

Authors:  Qiu Shi; Zhehui Liao; Zhili Liu; Jiajia Wen; Chenguang Li; Jiamin He; Jiazhen Deng; Shan Cen; Tongxiang Cao; Jinming Zhou; Shifa Zhu
Journal:  Nat Commun       Date:  2022-07-29       Impact factor: 17.694

7.  Dearomative di- and trifunctionalization of aryl sulfoxides via [5,5]-rearrangement.

Authors:  Mengjie Hu; Yanping Liu; Yuchen Liang; Taotao Dong; Lichun Kong; Ming Bao; Zhi-Xiang Wang; Bo Peng
Journal:  Nat Commun       Date:  2022-08-11       Impact factor: 17.694

8.  Carbene-catalyzed enantioselective annulation of dinucleophilic hydrazones and bromoenals for access to aryl-dihydropyridazinones and related drugs.

Authors:  Bivas Mondal; Rakesh Maiti; Xing Yang; Jun Xu; Weiyi Tian; Jia-Lei Yan; Xiangyang Li; Yonggui Robin Chi
Journal:  Chem Sci       Date:  2021-05-17       Impact factor: 9.825

9.  Construction of spirocarbocycles via gold-catalyzed intramolecular dearomatization of naphthols.

Authors:  Wen-Ting Wu; Ren-Qi Xu; Liming Zhang; Shu-Li You
Journal:  Chem Sci       Date:  2016-02-02       Impact factor: 9.825
  9 in total

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