Literature DB >> 25711491

Fixation of atmospheric carbon dioxide by ruthenium complexes bearing an NHC-based pincer ligand: formation of a methylcarbonato complex and its methylation.

Yasuhiro Arikawa1, Takuo Nakamura, Shinji Ogushi, Kazushige Eguchi, Keisuke Umakoshi.   

Abstract

A methylcarbonato ruthenium complex was prepared by capture of CO2 from air using the (CNC)(bpy)Ru scaffold. The methylcarbonato complex was relatively inert to decarboxylation. Treatments with methylating reagents released dimethylcarbonate.

Entities:  

Year:  2015        PMID： 25711491     DOI： 10.1039/c5dt00476d

Source DB:  PubMed          Journal:  Dalton Trans        ISSN： 1477-9226            Impact factor:   4.390


  2 in total

1.  CO2 capture by Mn(i) and Re(i) complexes with a deprotonated triethanolamine ligand.

Authors:  Hiroki Koizumi; Hiroyuki Chiba; Ayumi Sugihara; Munetaka Iwamura; Koichi Nozaki; Osamu Ishitani
Journal:  Chem Sci       Date:  2019-01-17       Impact factor: 9.825

2.  Electrocatalytic reduction of low concentration CO2.

Authors:  Hiromu Kumagai; Tetsuya Nishikawa; Hiroki Koizumi; Taiki Yatsu; Go Sahara; Yasuomi Yamazaki; Yusuke Tamaki; Osamu Ishitani
Journal:  Chem Sci       Date:  2018-11-12       Impact factor: 9.825
  2 in total

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