Literature DB >> 25710453

Carboranes in the chemist's toolbox.

Russell N Grimes1.   

Abstract

Once seldom encountered outside of a few laboratories, carboranes are now everywhere, playing a role in the development of a broad range of technologies encompassing organic synthesis, radionuclide handling, drug design, heat-resistant polymers, cancer therapy, nanomaterials, catalysis, metal-organic frameworks, molecular machines, batteries, electronic devices, and more. This perspective highlights selected examples in which the special attributes of carboranes and metallacarboranes are being exploited for targeted purposes in the laboratory and in the wider world.

Entities:  

Year:  2015        PMID: 25710453     DOI: 10.1039/c5dt00231a

Source DB:  PubMed          Journal:  Dalton Trans        ISSN: 1477-9226            Impact factor:   4.390


  13 in total

1.  Synthesis of 9-borafluorene analogues featuring a three-dimensional 1,1'-bis(o-carborane) backbone.

Authors:  Sam Yruegas; Jonathan C Axtell; Kent O Kirlikovali; Alexander M Spokoyny; Caleb D Martin
Journal:  Chem Commun (Camb)       Date:  2019-03-05       Impact factor: 6.222

2.  Expansion of the (BB) 〉metallacycle with coinage metal cations: formation of B-M-Ru-B (M = Cu, Ag, Au) dimetalacyclodiboryls.

Authors:  Bennett J Eleazer; Mark D Smith; Alexey A Popov; Dmitry V Peryshkov
Journal:  Chem Sci       Date:  2018-02-05       Impact factor: 9.825

3.  Ruthenacarborane-Phenanthroline Derivatives as Potential Metallodrugs.

Authors:  Martin Kellert; Imola Sárosi; Rajathees Rajaratnam; Eric Meggers; Peter Lönnecke; Evamarie Hey-Hawkins
Journal:  Molecules       Date:  2020-05-15       Impact factor: 4.411

4.  Ir-catalyzed enantioselective B-H alkenylation for asymmetric synthesis of chiral-at-cage o‑carboranes.

Authors:  Ruofei Cheng; Jie Zhang; Huifang Zhang; Zaozao Qiu; Zuowei Xie
Journal:  Nat Commun       Date:  2021-12-08       Impact factor: 14.919

5.  (BB)-Carboryne Complex of Ruthenium: Synthesis by Double B-H Activation at a Single Metal Center.

Authors:  Bennett J Eleazer; Mark D Smith; Alexey A Popov; Dmitry V Peryshkov
Journal:  J Am Chem Soc       Date:  2016-08-16       Impact factor: 15.419

6.  Rapid reversible borane to boryl hydride exchange by metal shuttling on the carborane cluster surface.

Authors:  Bennett J Eleazer; Mark D Smith; Alexey A Popov; Dmitry V Peryshkov
Journal:  Chem Sci       Date:  2017-05-25       Impact factor: 9.825

7.  [3-N2-o-C2B10H11][BF4]: a useful synthon for multiple cage boron functionalizations of o-carborane.

Authors:  Da Zhao; Zuowei Xie
Journal:  Chem Sci       Date:  2016-06-08       Impact factor: 9.825

8.  Highly selective palladium-catalyzed one-pot, five-fold B-H/C-H cross coupling of monocarboranes with alkenes.

Authors:  Yunjun Shen; Kang Zhang; Xuewei Liang; Rakesh Dontha; Simon Duttwyler
Journal:  Chem Sci       Date:  2019-03-04       Impact factor: 9.825

9.  Electrochemical B-H Nitrogenation: Access to Amino Acid and BODIPY-Labeled nido-Carboranes.

Authors:  Long Yang; Becky Bongsuiru Jei; Alexej Scheremetjew; Rositha Kuniyil; Lutz Ackermann
Journal:  Angew Chem Int Ed Engl       Date:  2020-11-17       Impact factor: 15.336

10.  Regioselective B(3,4)-H arylation of o-carboranes by weak amide coordination at room temperature.

Authors:  Yu-Feng Liang; Long Yang; Becky Bongsuiru Jei; Rositha Kuniyil; Lutz Ackermann
Journal:  Chem Sci       Date:  2020-05-05       Impact factor: 9.825

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