Literature DB >> 25705853

Cu-catalyzed asymmetric addition of sp²-hybridized zirconium nucleophiles to racemic allyl bromides.

Mireia Sidera1, Stephen P Fletcher.   

Abstract

Alkenylzirconium nucleophiles made in situ by the hydrozirconation of terminal alkynes undergo dynamic kinetic asymmetric allylic alkenylation with racemic allyl bromides to give enantioenriched products.

Entities:  

Year:  2015        PMID： 25705853     DOI： 10.1039/c5cc00421g

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  5 in total

1.  Advances in Stereoconvergent Catalysis from 2005 to 2015: Transition-Metal-Mediated Stereoablative Reactions, Dynamic Kinetic Resolutions, and Dynamic Kinetic Asymmetric Transformations.

Authors:  Vikram Bhat; Eric R Welin; Xuelei Guo; Brian M Stoltz
Journal:  Chem Rev       Date:  2017-02-06       Impact factor: 60.622

2.  Rhodium-catalysed asymmetric allylic arylation of racemic halides with arylboronic acids.

Authors:  Mireia Sidera; Stephen P Fletcher
Journal:  Nat Chem       Date:  2015-10-12       Impact factor: 24.427

3.  Asymmetric Suzuki-Miyaura coupling of heterocycles via Rhodium-catalysed allylic arylation of racemates.

Authors:  Philipp Schäfer; Thomas Palacin; Mireia Sidera; Stephen P Fletcher
Journal:  Nat Commun       Date:  2017-06-13       Impact factor: 14.919

4.  Highly Enantioselective Hiyama Cross-Coupling via Rh-Catalyzed Allylic Arylation of Racemic Allyl Chlorides.

Authors:  Jesús González; Philipp Schäfer; Stephen P Fletcher
Journal:  Organometallics       Date:  2019-05-10       Impact factor: 3.876

5.  Copper-catalysed asymmetric allylic alkylation of alkylzirconocenes to racemic 3,6-dihydro-2H-pyrans.

Authors:  Emeline Rideau; Stephen P Fletcher
Journal:  Beilstein J Org Chem       Date:  2015-12-03       Impact factor: 2.883
  5 in total

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