Literature DB >> 25700333

Why are the {Cu4N4} rings in copper(I) phosphinimide clusters [Cu{μ-N = PR3}]4 (R = NMe3 or Ph) planar?

Thomas P Robinson1, Richard D Price, Matthew G Davidson, Mark A Fox, Andrew L Johnson.   

Abstract

The copper phosphinimide complexes [Cu{μ-N[double bond, length as m-dash]PR3}]4 (1, R = NMe2 and 2, R = Ph) were obtained in good yields from the reactions of Cu[Mes] (Mes = mesityl, C6H2Me3-2,4,6) with the corresponding iminophosphoranes, HNPR3. The molecular structures of 1 and 2 reveal the presence of planar eight-membered {Cu4N4} rings which contrasts with the saddle-shaped {M4N4} rings found in related metal phosphinimide complexes. According to computations, there is negligible aromaticity in the planar {Cu4N4} rings in 1 and 2 and the saddle shape observed in related {M4N4} rings is due to steric factors.

Entities:  

Year:  2015        PMID: 25700333     DOI: 10.1039/c5dt00255a

Source DB:  PubMed          Journal:  Dalton Trans        ISSN: 1477-9226            Impact factor:   4.390


  1 in total

1.  Metal exchange in lithiocuprates: implications for our understanding of structure and reactivity.

Authors:  Andrew J Peel; Ryan Ackroyd; Andrew E H Wheatley
Journal:  Chem Sci       Date:  2017-05-04       Impact factor: 9.825

  1 in total

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