Warning: Undefined array key "mm" in /www/wwwroot/www.ai-bt.com/si.php on line 10 Deprecated: trim(): Passing null to parameter #1 ($string) of type string is deprecated in /www/wwwroot/www.ai-bt.com/si.php on line 10 Iron-catalyzed asymmetric hydrosilylation of 1,1-disubstituted alkenes.

Literature DB >> 25693877

Iron-catalyzed asymmetric hydrosilylation of 1,1-disubstituted alkenes.

Jianhui Chen¹, Biao Cheng, Minyi Cao, Zhan Lu.

Abstract

The highly regio- and enantioselective iron-catalyzed anti-Markovnikov hydrosilylation of 1,1-disubstituted aryl alkenes was developed using iminopyridine oxazoline ligands to afford chiral organosilanes. Additional derivatization of these products lead to chiral organosilanols, cyclic silanes, phenol derivatives, and 3-substituted 2,3-dihydrobenzofurans.

Entities: Chemical

Keywords: arenes; asymmetric catalysis; iron; silicon; synthetic methods

Year: 2015 PMID： 25693877 DOI： 10.1002/anie.201411884

Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336

Keyword Cloud
Cited

16 in total

1. Silylation reactions on nanoporous gold via homolytic Si-H activation of silanes.

Authors: Hongbo Li; Huifang Guo; Zhiwen Li; Cai Wu; Jing Li; Chunliang Zhao; Shuangxi Guo; Yi Ding; Wei He; Yadong Li
Journal: Chem Sci Date: 2018-04-30 Impact factor: 9.825

2. Selective Cobalt-Catalyzed Reduction of Terminal Alkenes and Alkynes Using (EtO)₂Si(Me)H as a Stoichiometric Reductant.

Authors: Balaram Raya; Souvagya Biswas; T V RajanBabu
Journal: ACS Catal Date: 2016-08-12 Impact factor: 13.084

3. Ir-Catalyzed Enantioselective, Intramolecular Silylation of Methyl C-H Bonds.

Authors: Bo Su; John F Hartwig
Journal: J Am Chem Soc Date: 2017-08-25 Impact factor: 15.419

4. Control of Selectivity through Synergy between Catalysts, Silanes and Reaction Conditions in Cobalt-Catalyzed Hydrosilylation of Dienes and Terminal Alkenes.

Authors: Balaram Raya; Stanley Jing; T V RajanBabu
Journal: ACS Catal Date: 2017-01-18 Impact factor: 13.084

5. Regioselective aerobic oxidative Heck reactions with electronically unbiased alkenes: efficient access to α-alkyl vinylarenes.

Authors: Changwu Zheng; Shannon S Stahl
Journal: Chem Commun (Camb) Date: 2015-08-18 Impact factor: 6.222

10. A β-diketiminate manganese catalyst for alkene hydrosilylation: substrate scope, silicone preparation, and mechanistic insight.

Authors: Tufan K Mukhopadhyay; Marco Flores; Thomas L Groy; Ryan J Trovitch
Journal: Chem Sci Date: 2018-08-15 Impact factor: 9.825

Iron-catalyzed asymmetric hydrosilylation of 1,1-disubstituted alkenes.

1. Silylation reactions on nanoporous gold via homolytic Si-H activation of silanes.

2. Selective Cobalt-Catalyzed Reduction of Terminal Alkenes and Alkynes Using (EtO)₂Si(Me)H as a Stoichiometric Reductant.

3. Ir-Catalyzed Enantioselective, Intramolecular Silylation of Methyl C-H Bonds.

4. Control of Selectivity through Synergy between Catalysts, Silanes and Reaction Conditions in Cobalt-Catalyzed Hydrosilylation of Dienes and Terminal Alkenes.

5. Regioselective aerobic oxidative Heck reactions with electronically unbiased alkenes: efficient access to α-alkyl vinylarenes.

6. Asymmetric Copper Hydride-Catalyzed Markovnikov Hydrosilylation of Vinylarenes and Vinyl Heterocycles.

7. Manganese-Catalyzed Asymmetric Hydrosilylation of Aryl Ketones.

8. Ligands with 1,10-phenanthroline scaffold for highly regioselective iron-catalyzed alkene hydrosilylation.

9. Asymmetric remote C-H borylation of internal alkenes via alkene isomerization.

10. A β-diketiminate manganese catalyst for alkene hydrosilylation: substrate scope, silicone preparation, and mechanistic insight.