Literature DB >> 25693784

Cycloparaphenylene-based ionic donor-acceptor supramolecule: isolation and characterization of Li⁺@C60⊂[10]CPP.

Hiroshi Ueno1, Taishi Nishihara, Yasutomo Segawa, Kenichiro Itami.   

Abstract

The first cycloparaphenylene (CPP)-based ionic donor-acceptor supramolecule Li(+)@C60⊂[10]CPP⋅X(-) has been synthesized. X-ray crystallography not only confirmed the molecular structure of Li(+)@C60⊂[10]CPP⋅X(-) but also uncovered the formation of a unique ionic crystal. The strong charge-transfer interaction between [10]CPP and Li(+)@C60, which was confirmed by electrochemical measurement and spectroscopic analyses, caused significant delocalization of the positive charge across the entire complex.
© 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  charge transfer; cycloparaphenylenes; ionic supramolecule; lithium ion encapsulated fullerene

Mesh:

Substances:

Year:  2015        PMID: 25693784     DOI: 10.1002/anie.201500544

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN: 1433-7851            Impact factor:   15.336


  11 in total

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2.  Synthesis and properties of [8]-, [10]-, [12]-, and [16]cyclo-1,4-naphthylenes.

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3.  π-extended [12]cycloparaphenylenes: from a hexaphenylbenzene cyclohexamer to its unexpected C2-symmetric congener.

Authors:  Florian E Golling; Silvio Osella; Martin Quernheim; Manfred Wagner; David Beljonne; Klaus Müllen
Journal:  Chem Sci       Date:  2015-09-08       Impact factor: 9.825

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Journal:  Nat Commun       Date:  2018-05-08       Impact factor: 14.919

5.  Cycloparaphenylene as a molecular porous carbon solid with uniform pores exhibiting adsorption-induced softness.

Authors:  Hirotoshi Sakamoto; Toshihiko Fujimori; Xiaolin Li; Katsumi Kaneko; Kai Kan; Noriaki Ozaki; Yuh Hijikata; Stephan Irle; Kenichiro Itami
Journal:  Chem Sci       Date:  2016-03-09       Impact factor: 9.825

Review 6.  The Supramolecular Chemistry of Cycloparaphenylenes and Their Analogs.

Authors:  Dapeng Lu; Qiang Huang; Shengda Wang; Jinyi Wang; Pingsen Huang; Pingwu Du
Journal:  Front Chem       Date:  2019-10-09       Impact factor: 5.221

7.  Comparison Between Electride Characteristics of Li3@B40 and Li3@C60.

Authors:  Prasenjit Das; Pratim Kumar Chattaraj
Journal:  Front Chem       Date:  2021-03-15       Impact factor: 5.221

8.  Structural deformation and host-guest properties of doubly-reduced cycloparaphenylenes, [n]CPPs2- (n = 6, 8, 10, and 12).

Authors:  Zheng Zhou; Zheng Wei; Tobias A Schaub; Ramesh Jasti; Marina A Petrukhina
Journal:  Chem Sci       Date:  2020-08-10       Impact factor: 9.825

9.  Electrochemical reduction of cationic Li+@C60 to neutral Li+@C60˙-: isolation and characterisation of endohedral [60]fulleride.

Authors:  Hiroshi Ueno; Shinobu Aoyagi; Yu Yamazaki; Kei Ohkubo; Naohiko Ikuma; Hiroshi Okada; Tatsuhisa Kato; Yutaka Matsuo; Shunichi Fukuzumi; Ken Kokubo
Journal:  Chem Sci       Date:  2016-06-20       Impact factor: 9.825

10.  Towards pi-extended cycloparaphenylenes as seeds for CNT growth: investigating strain relieving ring-openings and rearrangements.

Authors:  Thomas J Sisto; Lev N Zakharov; Brittany M White; Ramesh Jasti
Journal:  Chem Sci       Date:  2016-02-18       Impact factor: 9.825

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