Literature DB >> 25692320

Metal-free oxidative functionalization of C(sp(3))-H bond adjacent to oxygen and radical addition to olefins.

Wei Zhou1, Ping Qian, Jincan Zhao, Hong Fang, Jianlin Han, Yi Pan.   

Abstract

A DTBP-promoted oxidative functionalization of a C(sp(3))-H bond adjacent to oxygen and intermolecular radical addition to olefins without use of any metal catalyst or photoredox catalysis is reported. The reaction has a wide scope of olefin, alcohol, and cycloether substrates, which provides an easy way for direct preparation of α,ω-amino alcohols.

Entities:  

Year:  2015        PMID： 25692320     DOI： 10.1021/acs.orglett.5b00088

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  4 in total

1.  Metal-free alcohol-directed regioselective heteroarylation of remote unactivated C(sp3)-H bonds.

Authors:  Xinxin Wu; Hong Zhang; Nana Tang; Zhen Wu; Dongping Wang; Meishan Ji; Yan Xu; Min Wang; Chen Zhu
Journal:  Nat Commun       Date:  2018-08-21       Impact factor: 14.919

2.  Visible light-induced direct α C-H functionalization of alcohols.

Authors:  Linbin Niu; Jiamei Liu; Xing-An Liang; Shengchun Wang; Aiwen Lei
Journal:  Nat Commun       Date:  2019-01-28       Impact factor: 14.919

3.  The Ag-promoted α-C-H arylation of alcohols.

Authors:  Shoufeng Wang; Shuya Xing; Yingying Zhang; Yafei Fan; Huaiqing Zhao; Jianfeng Wang; Shuxiang Zhang; Wengui Wang
Journal:  RSC Adv       Date:  2019-12-17       Impact factor: 4.036

4.  Cascade alkylarylation of substituted N-allylbenzamides for the construction of dihydroisoquinolin-1(2H)-ones and isoquinoline-1,3(2H,4H)-diones.

Authors:  Ping Qian; Bingnan Du; Wei Jiao; Haibo Mei; Jianlin Han; Yi Pan
Journal:  Beilstein J Org Chem       Date:  2016-02-17       Impact factor: 2.883
  4 in total

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