| Literature DB >> 25689834 |
Julien Rodriguez1, Isabelle Beurroies, Thierry Loiseau, Renaud Denoyel, Philip L Llewellyn.
Abstract
In any process, the heat exchanged is an essential property required in its development. Whilst the work related to structural transitions of some flexible metal-organic frameworks (MOFs) has been quantified and linked with potential applications such as molecular springs or shock absorbers, the heat related to such transitions has never been directly measured. This has now been carried out with MIL-53(Al) using specifically devised calorimetry experiments. We project the importance of these heats in devices such as molecular springs or dampers.Entities:
Keywords: calorimetry; heat determination; mechanical properties; metal-organic frameworks; molecular springs
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Year: 2015 PMID: 25689834 DOI: 10.1002/anie.201411202
Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN: 1433-7851 Impact factor: 15.336