Literature DB >> 25687020

Enantioselective synthesis of planar-chiral benzosiloloferrocenes by Rh-catalyzed intramolecular C-H silylation.

Takanori Shibata1, Tsubasa Shizuno, Tomoya Sasaki.   

Abstract

The first synthesis of planar-chiral benzosiloloferrocenes was achieved by the intramolecular reaction of 2-(dimethylhydrosilyl)arylferrocenes. The enantioselective cross dehydrogenative coupling of an sp(2) C-H bond of ferrocene with a Si-H bond proceeded efficiently with the use of a Rh-chiral diene catalyst.

Entities:  

Year:  2015        PMID： 25687020     DOI： 10.1039/c5cc00723b

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  9 in total

1.  A Chiral Nitrogen Ligand for Enantioselective, Iridium-Catalyzed Silylation of Aromatic C-H Bonds.

Authors:  Bo Su; Tai-Gang Zhou; Xian-Wei Li; Xiao-Ru Shao; Pei-Lin Xu; Wen-Lian Wu; John F Hartwig; Zhang-Jie Shi
Journal:  Angew Chem Int Ed Engl       Date:  2016-12-15       Impact factor: 15.336

2.  Mechanistic Studies on Rhodium-Catalyzed Enantioselective Silylation of Aryl C-H Bonds.

Authors:  Taegyo Lee; John F Hartwig
Journal:  J Am Chem Soc       Date:  2017-03-24       Impact factor: 15.419

3.  Ir-Catalyzed Enantioselective, Intramolecular Silylation of Methyl C-H Bonds.

Authors:  Bo Su; John F Hartwig
Journal:  J Am Chem Soc       Date:  2017-08-25       Impact factor: 15.419

4.  Rhodium-catalyzed enantioselective silylation of arene C-H bonds: desymmetrization of diarylmethanols.

Authors:  Taegyo Lee; Tyler W Wilson; Robert Berg; Per Ryberg; John F Hartwig
Journal:  J Am Chem Soc       Date:  2015-05-20       Impact factor: 15.419

5.  Enantioselective remote meta-C-H arylation and alkylation via a chiral transient mediator.

Authors:  Hang Shi; Alastair N Herron; Ying Shao; Qian Shao; Jin-Quan Yu
Journal:  Nature       Date:  2018-06-18       Impact factor: 49.962

Review 6.  A comprehensive overview of directing groups applied in metal-catalysed C-H functionalisation chemistry.

Authors:  Carlo Sambiagio; David Schönbauer; Remi Blieck; Toan Dao-Huy; Gerit Pototschnig; Patricia Schaaf; Thomas Wiesinger; Muhammad Farooq Zia; Joanna Wencel-Delord; Tatiana Besset; Bert U W Maes; Michael Schnürch
Journal:  Chem Soc Rev       Date:  2018-08-28       Impact factor: 54.564

Review 7.  Development of Chiral Ligands for the Transition-Metal-Catalyzed Enantioselective Silylation and Borylation of C-H Bonds.

Authors:  Bo Su; John F Hartwig
Journal:  Angew Chem Int Ed Engl       Date:  2021-12-21       Impact factor: 16.823

8.  Thioketone-directed rhodium(I) catalyzed enantioselective C-H bond arylation of ferrocenes.

Authors:  Zhong-Jian Cai; Chen-Xu Liu; Qiang Wang; Qing Gu; Shu-Li You
Journal:  Nat Commun       Date:  2019-09-13       Impact factor: 14.919

Review 9.  Advances in Synthesis of π-Extended Benzosilole Derivatives and Their Analogs.

Authors:  Tuan Thanh Dang; Hue Minh Thi Nguyen; Hien Nguyen; Tran Ngoc Dung; Minh Tho Nguyen; Wim Dehaen
Journal:  Molecules       Date:  2020-01-27       Impact factor: 4.411
  9 in total

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