Literature DB >> 25683335

Thermodynamics of cellulose dissolution in an imidazolium acetate ionic liquid.

J-M Andanson1, A A H Pádua, M F Costa Gomes.   

Abstract

The heat of dissolution of cellulose in one imidazolium acetate ionic liquid was determined experimentally. The value of -132 ± 8 J g(-1) indicates that the dissolution is exothermal thus confirming energetically favourable cellulose-ionic liquid interactions but indicating that an increase in temperature does not thermodynamically favour the dissolution process.

Entities:  

Year:  2015        PMID： 25683335     DOI： 10.1039/c4cc10249e

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  3 in total

1.  NMR and Rheological Study of Anion Size Influence on the Properties of Two Imidazolium-based Ionic Liquids.

Authors:  Stephen M Green; Michael E Ries; Jamie Moffat; Tatiana Budtova
Journal:  Sci Rep       Date:  2017-08-21       Impact factor: 4.379

Review 2.  Towards a molecular understanding of cellulose dissolution in ionic liquids: anion/cation effect, synergistic mechanism and physicochemical aspects.

Authors:  Yao Li; Jianji Wang; Xiaomin Liu; Suojiang Zhang
Journal:  Chem Sci       Date:  2018-03-26       Impact factor: 9.825

3.  Irregular solution thermodynamics of wood pulp in the superbase ionic liquid [m-TBDH][AcO].

Authors:  Gordon W Driver; Ilkka A Kilpeläinen
Journal:  RSC Adv       Date:  2020-11-19       Impact factor: 4.036
  3 in total

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