Literature DB >> 25683286

Dinuclear zinc catalysts with unprecedented activities for the copolymerization of cyclohexene oxide and CO2.

S Kissling1, M W Lehenmeier, P T Altenbuchner, A Kronast, M Reiter, P Deglmann, U B Seemann, B Rieger.   

Abstract

A variety of new dinuclear zinc catalysts was developed and tested for the copolymerization of cyclohexene oxide and carbon dioxide. Electron-withdrawing groups thereby led to unprecedented activities with turnover frequencies up to 155,000 h(-1). These are by far the highest polymerization rates ever reported for the copolymerization of cyclohexene oxide and CO2.

Entities:  

Year:  2015        PMID： 25683286     DOI： 10.1039/c5cc00784d

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  11 in total

1.  Aluminum porphyrins with quaternary ammonium halides as catalysts for copolymerization of cyclohexene oxide and CO2: metal-ligand cooperative catalysis.

Authors:  Jingyuan Deng; Manussada Ratanasak; Yuma Sako; Hideki Tokuda; Chihiro Maeda; Jun-Ya Hasegawa; Kyoko Nozaki; Tadashi Ema
Journal:  Chem Sci       Date:  2020-05-18       Impact factor: 9.825

2.  Crystalline CO2-based polycarbonates prepared from racemic catalyst through intramolecularly interlocked assembly.

Authors:  Ye Liu; Wei-Min Ren; Wei-Ping Zhang; Rong-Rong Zhao; Xiao-Bing Lu
Journal:  Nat Commun       Date:  2015-10-15       Impact factor: 14.919

Review 3.  Catalysts for CO2/epoxide ring-opening copolymerization.

Authors:  G Trott; P K Saini; C K Williams
Journal:  Philos Trans A Math Phys Eng Sci       Date:  2016-02-28       Impact factor: 4.226

4.  Catalytic Chain Transfer Copolymerization of Propylene Oxide and CO2 using Zinc Glutarate Catalyst.

Authors:  Jakob Marbach; Theresa Höfer; Nick Bornholdt; Gerrit A Luinstra
Journal:  ChemistryOpen       Date:  2019-06-11       Impact factor: 2.911

5.  Heterotrimetallic Carbon Dioxide Copolymerization and Switchable Catalysts: Sodium is the Key to High Activity and Unusual Selectivity.

Authors:  Alex J Plajer; Charlotte K Williams
Journal:  Angew Chem Int Ed Engl       Date:  2021-05-10       Impact factor: 15.336

6.  Copolymerization of CO2 and epoxides mediated by zinc organyls.

Authors:  Christoph Wulf; Ulrike Doering; Thomas Werner
Journal:  RSC Adv       Date:  2018-01-18       Impact factor: 3.361

7.  A Lewis acid β-diiminato-zinc-complex as all-rounder for co- and terpolymerisation of various epoxides with carbon dioxide.

Authors:  M Reiter; S Vagin; A Kronast; C Jandl; B Rieger
Journal:  Chem Sci       Date:  2016-11-17       Impact factor: 9.825

8.  Dizinc Lactide Polymerization Catalysts: Hyperactivity by Control of Ligand Conformation and Metallic Cooperativity.

Authors:  Arnaud Thevenon; Charles Romain; Michael S Bennington; Andrew J P White; Hannah J Davidson; Sally Brooker; Charlotte K Williams
Journal:  Angew Chem Int Ed Engl       Date:  2016-06-13       Impact factor: 15.336

9.  Heterodinuclear Mg(II)M(II) (M=Cr, Mn, Fe, Co, Ni, Cu and Zn) Complexes for the Ring Opening Copolymerization of Carbon Dioxide/Epoxide and Anhydride/Epoxide.

Authors:  Natalia V Reis; Arron C Deacy; Gloria Rosetto; Christopher B Durr; Charlotte K Williams
Journal:  Chemistry       Date:  2022-02-17       Impact factor: 5.020

Review 10.  Heterocycle/Heteroallene Ring-Opening Copolymerization: Selective Catalysis Delivering Alternating Copolymers.

Authors:  Alex J Plajer; Charlotte K Williams
Journal:  Angew Chem Int Ed Engl       Date:  2021-10-19       Impact factor: 16.823
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