Literature DB >> 25679825

Ligand-free, palladium-catalyzed dihydrogen generation from TMDS: dehalogenation of aryl halides on water.

Anish Bhattacharjya1, Piyatida Klumphu, Bruce H Lipshutz.   

Abstract

A mild and environmentally attractive dehalogenation of functionalized aryl halides has been developed using nanoparticles formed from PdCl2 in the presence of tetramethyldisiloxane (TMDS) on water. The active catalyst and reaction medium can be recycled. This method can also be applied to cascade reactions in a one-pot sequence.

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Year:  2015        PMID: 25679825     DOI: 10.1021/ol5037369

Source DB:  PubMed          Journal:  Org Lett        ISSN: 1523-7052            Impact factor:   6.005


  2 in total

1.  Catalytic Reductions Without External Hydrogen Gas: Broad Scope Hydrogenations with Tetrahydroxydiboron and a Tertiary Amine.

Authors:  Kirill A Korvinson; Hari K Akula; Casina T Malinchak; Dellamol Sebastian; Wei Wei; Tashrique A Khandaker; Magdalena R Andrzejewska; Barbara Zajc; Mahesh K Lakshman
Journal:  Adv Synth Catal       Date:  2019-11-13       Impact factor: 5.837

Review 2.  Multicomponent Reactions Accelerated by Aqueous Micelles.

Authors:  Daniel Paprocki; Arleta Madej; Dominik Koszelewski; Anna Brodzka; Ryszard Ostaszewski
Journal:  Front Chem       Date:  2018-10-22       Impact factor: 5.221

  2 in total

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