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Literature DB >> 25670391

Mechanism of water oxidation by [Ru(bda)(L)2]: the return of the "blue dimer".

Javier J Concepcion¹, Diane K Zhong, David J Szalda, James T Muckerman, Etsuko Fujita.

Abstract

We describe here a combined solution-surface-DFT calculations study for complexes of the type [Ru(bda)(L)2] including X-ray structure of intermediates and their reactivity, as well as pH-dependent electrochemistry and spectroelectrochemistry. These studies shed light on the mechanism of water oxidation by [Ru(bda)(L)2], revealing key features unavailable from solution studies with sacrificial oxidants.

Entities: Chemical

Year: 2015 PMID： 25670391 DOI： 10.1039/c4cc07968j

Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222

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Cited

11 in total

Review 1. Dye-sensitized solar cells strike back.

Authors: Ana Belén Muñoz-García; Iacopo Benesperi; Gerrit Boschloo; Javier J Concepcion; Jared H Delcamp; Elizabeth A Gibson; Gerald J Meyer; Michele Pavone; Henrik Pettersson; Anders Hagfeldt; Marina Freitag
Journal: Chem Soc Rev Date: 2021-11-15 Impact factor: 54.564

2. A supramolecular ruthenium macrocycle with high catalytic activity for water oxidation that mechanistically mimics photosystem II.

Authors: Marcus Schulze; Valentin Kunz; Peter D Frischmann; Frank Würthner
Journal: Nat Chem Date: 2016-05-02 Impact factor: 24.427

3. Structure-Activity Relationship for Di- up to Tetranuclear Macrocyclic Ruthenium Catalysts in Homogeneous Water Oxidation.

Authors: Dorothee Schindler; Ana-Lucia Meza-Chincha; Maximilian Roth; Frank Würthner
Journal: Chemistry Date: 2021-05-27 Impact factor: 5.020

4. Amphiphilic Oxo-Bridged Ruthenium "Green Dimer" for Water Oxidation.

Authors: Qing-Qing Yang; Xin Jiang; Bing Yang; Yang Wang; Chen-Ho Tung; Li-Zhu Wu
Journal: iScience Date: 2020-03-08

5. A diketopyrrolopyrrole dye-based dyad on a porous TiO₂ photoanode for solar-driven water oxidation.

Authors: Daniel Antón-García; Julien Warnan; Erwin Reisner
Journal: Chem Sci Date: 2020-09-25 Impact factor: 9.825

6. Impact of substituents on molecular properties and catalytic activities of trinuclear Ru macrocycles in water oxidation.

Authors: Ana-Lucia Meza-Chincha; Joachim O Lindner; Dorothee Schindler; David Schmidt; Ana-Maria Krause; Merle I S Röhr; Roland Mitrić; Frank Würthner
Journal: Chem Sci Date: 2020-04-29 Impact factor: 9.825

Mechanism of water oxidation by [Ru(bda)(L)2]: the return of the "blue dimer".

Review 1. Dye-sensitized solar cells strike back.

2. A supramolecular ruthenium macrocycle with high catalytic activity for water oxidation that mechanistically mimics photosystem II.

3. Structure-Activity Relationship for Di- up to Tetranuclear Macrocyclic Ruthenium Catalysts in Homogeneous Water Oxidation.

4. Amphiphilic Oxo-Bridged Ruthenium "Green Dimer" for Water Oxidation.

5. A diketopyrrolopyrrole dye-based dyad on a porous TiO₂ photoanode for solar-driven water oxidation.

6. Impact of substituents on molecular properties and catalytic activities of trinuclear Ru macrocycles in water oxidation.

7. Direct oxygen isotope effect identifies the rate-determining step of electrocatalytic OER at an oxidic surface.

Review 8. An Overview of Significant Achievements in Ruthenium-Based Molecular Water Oxidation Catalysis.

9. Stabilization of a molecular water oxidation catalyst on a dye-sensitized photoanode by a pyridyl anchor.

10. A Calix[4]arene-Based Cyclic Dinuclear Ruthenium Complex for Light-Driven Catalytic Water Oxidation.