Literature DB >> 25665602

Oxidative Heck desymmetrisation of 2,2-disubstituted cyclopentene-1,3-diones.

S E Walker1, C J C Lamb, N A Beattie, P Nikodemiak, A-L Lee.   

Abstract

Oxidative Heck couplings have been successfully developed for 2,2-disubstituted cyclopentene-1,3-diones. The direct coupling onto the 2,2-disubstituted cyclopentene-1,3-dione core provides a novel expedient way of enantioselectively desymmetrising all-carbon quaternary centres.

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Year:  2015        PMID: 25665602     DOI: 10.1039/c5cc00407a

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  1 in total

1.  Auto-Tandem Catalysis: PdII -Catalysed Dehydrogenation/Oxidative Heck Reaction of Cyclopentane-1,3-diones.

Authors:  Claire J C Lamb; Bryan G Nderitu; Gemma McMurdo; John M Tobin; Filipe Vilela; Ai-Lan Lee
Journal:  Chemistry       Date:  2017-11-30       Impact factor: 5.236

  1 in total

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