Literature DB >> 25663350

Manganese-catalyzed synthesis of cis-β-amino acid esters through organometallic C-H activation of ketimines.

Weiping Liu1, Daniel Zell, Michael John, Lutz Ackermann.   

Abstract

Manganese-catalyzed CH functionalization reactions of ketimines set the stage for the expedient synthesis of cis-β-amino acid esters through site- and regioselective alkene annulations. The organometallic CH activation occurred efficiently with high functional group tolerance, delivering densely functionalized β-amino acid derivatives with ample scope.
© 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  CH activation; amino acids; manganese; reaction mechanisms; selectivity

Mesh：

Substances：

Year:  2015        PMID： 25663350     DOI： 10.1002/anie.201411808

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  10 in total

1.  Transition-Metal-Catalyzed C-H Bond Addition to Carbonyls, Imines, and Related Polarized π Bonds.

Authors:  Joshua R Hummel; Jeffrey A Boerth; Jonathan A Ellman
Journal:  Chem Rev       Date:  2016-12-12       Impact factor: 60.622

2.  Cobalt-Catalyzed, Aminoquinoline-Directed Functionalization of Phosphinic Amide sp2 C-H Bonds.

Authors:  Tung Thanh Nguyen; Liene Grigorjeva; Olafs Daugulis
Journal:  ACS Catal       Date:  2015-12-22       Impact factor: 13.084

3.  Convergent Synthesis of α-Branched Amines by Transition-Metal-Catalyzed C-H Bond Additions to Imines.

Authors:  Joshua R Hummel; Jonathan A Ellman
Journal:  Isr J Chem       Date:  2017-06-29       Impact factor: 3.333

4.  Rh(III)-Catalyzed Diastereoselective C-H Bond Addition/Cyclization Cascade of Enone Tethered Aldehydes.

Authors:  Jeffrey A Boerth; Jonathan A Ellman
Journal:  Chem Sci       Date:  2015-12-01       Impact factor: 9.825

5.  Manganese-catalyzed allylation via sequential C-H and C-C/C-Het bond activation.

Authors:  Qingquan Lu; Felix J R Klauck; Frank Glorius
Journal:  Chem Sci       Date:  2017-02-24       Impact factor: 9.825

6.  Rh(iii)-catalyzed spiroannulation of 3-arylquinoxalin-2(1H)-ones with alkynes: practical access to spiroquinoxalinones.

Authors:  Yuanfei Zhang; Ting Huang; Xinghua Li; Min Zhang; Ying Song; Kelin Huang; Weiping Su
Journal:  RSC Adv       Date:  2020-06-10       Impact factor: 3.361

7.  Mangana(iii/iv)electro-catalyzed C(sp3)-H azidation.

Authors:  Tjark H Meyer; Ramesh C Samanta; Antonio Del Vecchio; Lutz Ackermann
Journal:  Chem Sci       Date:  2020-12-28       Impact factor: 9.825

8.  Manganese(I)-Catalyzed C-H Activation: The Key Role of a 7-Membered Manganacycle in H-Transfer and Reductive Elimination.

Authors:  Nasiru P Yahaya; Kate M Appleby; Magdalene Teh; Conrad Wagner; Erik Troschke; Joshua T W Bray; Simon B Duckett; L Anders Hammarback; Jonathan S Ward; Jessica Milani; Natalie E Pridmore; Adrian C Whitwood; Jason M Lynam; Ian J S Fairlamb
Journal:  Angew Chem Int Ed Engl       Date:  2016-09-07       Impact factor: 15.336

9.  Aromatic C-H addition of ketones to imines enabled by manganese catalysis.

Authors:  Bingwei Zhou; Yuanyuan Hu; Ting Liu; Congyang Wang
Journal:  Nat Commun       Date:  2017-10-27       Impact factor: 14.919

10.  The [3+2] Annulation of CF3-Ketimines by Re Catalysis: Access to CF3-Containing Amino Heterocycles and Polyamides.

Authors:  Saisai Zhang; Xun-Yong Liu; Zhenbang Chang; Xinxin Qiao; Heng-Ying Xiong; Guangwu Zhang
Journal:  iScience       Date:  2020-10-20
  10 in total

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