| Literature DB >> 25662906 |
Kenji Watanabe1, Toshikane Suzuki, Hiroaki Kitagishi, Koji Kano.
Abstract
The reaction between hydrosulphide (SH(-)) and a haemoglobin model compound, composed of a Fe(III)-porphyrin and a cyclodextrin dimer possessing a pyridine-linker (met-hemoCD3), was studied. Met-hemoCD3 formed a stable (SH(-))-met-hemoCD3 complex in oxygen-free neutral aqueous solution. In the presence of O2, reversible ligand exchange between (SH(-))-met-hemoCD3 (Fe(III)) and O2-hemoCD3 (Fe(II)) occurred.Entities:
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Year: 2015 PMID: 25662906 DOI: 10.1039/c5cc00057b
Source DB: PubMed Journal: Chem Commun (Camb) ISSN: 1359-7345 Impact factor: 6.222