| Literature DB >> 25658134 |
Daniele Mammoli1, Basile Vuichoud, Aurélien Bornet, Jonas Milani, Jean-Nicolas Dumez, Sami Jannin, Geoffrey Bodenhausen.
Abstract
We show that an imbalance between the populations of singlet (S) and triplet (T) states in pairs of magnetically equivalent spins can be generated by dissolution dynamic nuclear polarization. In partly deuterated ethanol (CD3(13)CH2OD), this T/S imbalance can be transferred by cross-relaxation to observable, enhanced signals of protons and coupled (13)C.Entities:
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Year: 2015 PMID: 25658134 DOI: 10.1021/jp512128c
Source DB: PubMed Journal: J Phys Chem B ISSN: 1520-5207 Impact factor: 2.991