| Literature DB >> 25655768 |
Elsa Alvarez1, Nathalie Guillou, Charlotte Martineau, Bart Bueken, Ben Van de Voorde, Clément Le Guillouzer, Paul Fabry, Farid Nouar, Francis Taulelle, Dirk de Vos, Jong-San Chang, Kyoung Ho Cho, Naseem Ramsahye, Thomas Devic, Marco Daturi, Guillaume Maurin, Christian Serre.
Abstract
The synthesis of the commercially available aluminum fumarate sample A520 has been optimized and its structure analyzed through a combination of powder diffraction, solid-state NMR spectroscopy, molecular simulation, IR spectroscopy, and thermal analysis. A520 is an analogue of the MIL-53(Al)-BDC solid, but with a more rigid behavior. The differences between the commercial and the optimized samples in terms of defects have been investigated by in situ IR spectroscopy and correlated to their catalytic activity for ethanol dehydration.Entities:
Keywords: X-ray diffraction; aluminum fumarate; metal-organic frameworks; modeling; solid state NMR spectroscopy
Year: 2015 PMID: 25655768 DOI: 10.1002/anie.201410459
Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN: 1433-7851 Impact factor: 15.336