Literature DB >> 25649958

Diastereoselective synthesis of O symmetric heterometallic cubic cages.

Yang Yang1, Jian-Hua Jia, Xiao-Li Pei, Hao Zheng, Zi-Ang Nan, Quan-Ming Wang.   

Abstract

Enantiopure chiral cubic cages have been diastereoselectively synthesized for the first time. Chiral amines lead to the isolation of O symmetric homochiral cubic cages, while an achiral amine gives a racemic mixture. CD enhancement is observed as a result of configuration rigidity.

Entities:  

Year:  2015        PMID： 25649958     DOI： 10.1039/c5cc00087d

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  2 in total

1.  Solvent Drives Switching between Λ and Δ Metal Center Stereochemistry of M8L6 Cubic Cages.

Authors:  Weichao Xue; Tanya K Ronson; Zifei Lu; Jonathan R Nitschke
Journal:  J Am Chem Soc       Date:  2022-04-01       Impact factor: 16.383

2.  Homochiral D4-symmetric metal-organic cages from stereogenic Ru(II) metalloligands for effective enantioseparation of atropisomeric molecules.

Authors:  Kai Wu; Kang Li; Ya-Jun Hou; Mei Pan; Lu-Yin Zhang; Ling Chen; Cheng-Yong Su
Journal:  Nat Commun       Date:  2016-02-03       Impact factor: 14.919
  2 in total

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