Literature DB >> 25648741

Metal-free radical oxidative decarboxylation/cyclization of acyl peroxides and 2-isocyanobiphenyls.

Changduo Pan1, Honglin Zhang, Jie Han, Yixiang Cheng, Chengjian Zhu.   

Abstract

A metal-free radical oxidative decarboxylation/cyclization of acyl peroxides and 2-isocyanobiphenyls was achieved, leading to 6-aryl phenanthridines as well as 6-alkyl phenanthridines in moderate to good yields. The procedure featured simple conditions and was metal-free and base free. It represents a practical approach to access 6-aryl/alkyl phenanthridines.

Entities:  

Year:  2015        PMID: 25648741     DOI: 10.1039/c4cc10015h

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  2 in total

1.  Iron catalyzed methylation and ethylation of vinyl arenes.

Authors:  Nengbo Zhu; Jianguo Zhao; Hongli Bao
Journal:  Chem Sci       Date:  2016-12-02       Impact factor: 9.825

2.  Oxidative Photocyclization of Aromatic Schiff Bases in Synthesis of Phenanthridines and Other Aza-PAHs.

Authors:  Martin Kos; Jaroslav Žádný; Jan Storch; Vladimír Církva; Petra Cuřínová; Jan Sýkora; Ivana Císařová; Febin Kuriakose; Igor V Alabugin
Journal:  Int J Mol Sci       Date:  2020-08-15       Impact factor: 5.923

  2 in total

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