Literature DB >> 25646601

Reductive arene ortho-silanolization of aromatic esters with hydridosilyl acetals.

Yuanda Hua1, Parham Asgari, Udaya Sree Dakarapu, Junha Jeon.   

Abstract

This work describes the design and application of a single-pot, reductive arene C-H silanolization of aromatic esters for synthesis of ortho-formyl arylsilanols. This strategy involves a sequence of two transition metal (Ir and Rh)-catalyzed reactions for reductive arene ortho-silylation directed by hydridosilyl acetals and hydrolysis.

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Year:  2015        PMID： 25646601     DOI： 10.1039/c4cc09850a

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  3 in total

1.  Aryne cycloaddition reactions of benzodioxasilines as aryne precursors generated by catalytic reductive ortho-C-H silylation of phenols with traceless acetal directing groups.

Authors:  Parham Asgari; Udaya Sree Dakarapu; Hiep H Nguyen; Junha Jeon
Journal:  Tetrahedron       Date:  2016-12-08       Impact factor: 2.457

2.  Catalytic Net Oxidative C-C Activation and Silylation of Cyclopropanols with a Traceless Acetal Directing Group.

Authors:  Thirupataiah Avullala; Hiep H Nguyen; Udaya Sree Dakarapu; Parham Asgari; Yuanda Hua; Junha Jeon
Journal:  ACS Catal       Date:  2022-01-18       Impact factor: 13.700

3.  Catalytic Reductive ortho-C-H Silylation of Phenols with Traceless, Versatile Acetal Directing Groups and Synthetic Applications of Dioxasilines.

Authors:  Yuanda Hua; Parham Asgari; Thirupataiah Avullala; Junha Jeon
Journal:  J Am Chem Soc       Date:  2016-06-16       Impact factor: 15.419
  3 in total

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